Wiley
Chemistry - A European Journal
,  volume 16 ,  issue 9 ,  pages 2696-2699

Diversity of Products in the Gold-Catalyzed Cyclization of 1-Epoxy-1-alkynylcyclopropanes by Using 1-Oxyallyl Cations

Publication type: Journal Article
Publication date: 2010-01-29
Wiley
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
A highly stereoselective AuCl3-catalyzed hydrative cyclization of 1-epoxy-1-alkynylcyclopropanes was observed for cis-epoxides. Since this cyclization produced 1-oxyallyl cations efficiently, we accomplished a two-step [4+2] annulation of epoxyalkynes with dienes and enones, to provide complex oxacyclic compounds with excellent diastereoselectivity (see scheme).
Found 
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GOST |
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GOST Copy
Yang C. Y. et al. Diversity of Products in the Gold-Catalyzed Cyclization of 1-Epoxy-1-alkynylcyclopropanes by Using 1-Oxyallyl Cations // Chemistry - A European Journal. 2010. Vol. 16. No. 9. pp. 2696-2699.
GOST all authors (up to 50) Copy
Yang C. Y., Lin M. S., Liao H. H., Liu R. Diversity of Products in the Gold-Catalyzed Cyclization of 1-Epoxy-1-alkynylcyclopropanes by Using 1-Oxyallyl Cations // Chemistry - A European Journal. 2010. Vol. 16. No. 9. pp. 2696-2699.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/chem.200903419
UR - https://doi.org/10.1002/chem.200903419
TI - Diversity of Products in the Gold-Catalyzed Cyclization of 1-Epoxy-1-alkynylcyclopropanes by Using 1-Oxyallyl Cations
T2 - Chemistry - A European Journal
AU - Yang, Chun Yao
AU - Lin, Min Shiun
AU - Liao, Hsuan Hung
AU - Liu, Rai-Shung
PY - 2010
DA - 2010/01/29
PB - Wiley
SP - 2696-2699
IS - 9
VL - 16
PMID - 20119997
SN - 0947-6539
SN - 1521-3765
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2010_Yang,
author = {Chun Yao Yang and Min Shiun Lin and Hsuan Hung Liao and Rai-Shung Liu},
title = {Diversity of Products in the Gold-Catalyzed Cyclization of 1-Epoxy-1-alkynylcyclopropanes by Using 1-Oxyallyl Cations},
journal = {Chemistry - A European Journal},
year = {2010},
volume = {16},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/chem.200903419},
number = {9},
pages = {2696--2699},
doi = {10.1002/chem.200903419}
}
MLA
Cite this
MLA Copy
Yang, Chun Yao, et al. “Diversity of Products in the Gold-Catalyzed Cyclization of 1-Epoxy-1-alkynylcyclopropanes by Using 1-Oxyallyl Cations.” Chemistry - A European Journal, vol. 16, no. 9, Jan. 2010, pp. 2696-2699. https://doi.org/10.1002/chem.200903419.