Chemistry - A European Journal, volume 18, issue 35, pages 10949-10953
Chemical and Photochemical Functionality of the First Molecular Bismuth Vanadium Oxide
Publication type: Journal Article
Publication date: 2012-07-24
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
Anionic metal oxide clusters, so‐called polyoxometalates, can be developed as molecular model compounds to mimic the chemical and photochemical reactivity of solid‐state metal oxides on the molecular level. Inspired by the well‐known visible‐light photocatalyst BiVO4, the first molecular bismuth vanadium oxide has been synthesized to investigate the chemical and photochemical similarities between the solid‐state and molecular compounds. The cluster H3[(Bi(dmso)3)4V13O40]⋅ca. 4 DMSO was obtained from simple precursors in almost quantitative yield. Structural analysis showed that the cluster shell is based on the unusual all‐vanadium ε‐Keggin framework [ε‐V12O40]15−, which is stabilized by coordination of four BiIII centers. The acidic character of the three cluster protons was demonstrated by titration studies. The cluster shows promising photocatalytic properties in visible‐light photooxidation reactions and has high activity (turnover number >1200), high quantum yield (Φ=7.6 %), and good recyclability, which make it a promising first example of a new class of heterometallic polyoxometalates.
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1 publication, 1.35%
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- We do not take into account publications without a DOI.
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Tucher J. et al. Chemical and Photochemical Functionality of the First Molecular Bismuth Vanadium Oxide // Chemistry - A European Journal. 2012. Vol. 18. No. 35. pp. 10949-10953.
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Tucher J., Nye L. C., Ivanovic-Burmazovic I., Notarnicola A., Streb C. Chemical and Photochemical Functionality of the First Molecular Bismuth Vanadium Oxide // Chemistry - A European Journal. 2012. Vol. 18. No. 35. pp. 10949-10953.
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TY - JOUR
DO - 10.1002/chem.201200404
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201200404
TI - Chemical and Photochemical Functionality of the First Molecular Bismuth Vanadium Oxide
T2 - Chemistry - A European Journal
AU - Tucher, Johannes
AU - Nye, Leanne C
AU - Ivanovic-Burmazovic, Ivana
AU - Notarnicola, Antonio
AU - Streb, Carsten
PY - 2012
DA - 2012/07/24 00:00:00
PB - Wiley
SP - 10949-10953
IS - 35
VL - 18
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2012_Tucher,
author = {Johannes Tucher and Leanne C Nye and Ivana Ivanovic-Burmazovic and Antonio Notarnicola and Carsten Streb},
title = {Chemical and Photochemical Functionality of the First Molecular Bismuth Vanadium Oxide},
journal = {Chemistry - A European Journal},
year = {2012},
volume = {18},
publisher = {Wiley},
month = {jul},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201200404},
number = {35},
pages = {10949--10953},
doi = {10.1002/chem.201200404}
}
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MLA
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Tucher, Johannes, et al. “Chemical and Photochemical Functionality of the First Molecular Bismuth Vanadium Oxide.” Chemistry - A European Journal, vol. 18, no. 35, Jul. 2012, pp. 10949-10953. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201200404.