Chemistry - A European Journal, volume 20, issue 38, pages 12037-12040
Catalytic Formation of Acrylate from Carbon Dioxide and Ethene
4
CREAVIS ‐ Science to Business, Evonik Industries AG, 1420/18, Paul Baumann‐Strasse 1, 45772 Marl (Germany)
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Publication type: Journal Article
Publication date: 2014-08-12
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
With regard to sustainability, carbon dioxide (CO2) is an attractive C1 building block. However, due to thermodynamic restrictions, reactions incorporating CO2 are relatively limited so far. One of the so-called "dream reactions" in this field is the catalytic oxidative coupling of CO2 and ethene and subsequent β-H elimination to form acrylic acid. This reaction has been studied intensely for decades. However up to this date no suitable catalytic process has been established. Here we show that the catalytic conversion of ethene and CO2 to acrylate is possible in the presence of a homogeneous nickel catalyst in combination with a "hard" Lewis acid. For the first time, catalytic conversion of CO2 and ethene to acrylate with turnover numbers (TON) of up to 21 was demonstrated.
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GOST
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Hendriksen C. et al. Catalytic Formation of Acrylate from Carbon Dioxide and Ethene // Chemistry - A European Journal. 2014. Vol. 20. No. 38. pp. 12037-12040.
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Hendriksen C., Pidko E. A., Yang G., Schäffner B., Vogt D. Catalytic Formation of Acrylate from Carbon Dioxide and Ethene // Chemistry - A European Journal. 2014. Vol. 20. No. 38. pp. 12037-12040.
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TY - JOUR
DO - 10.1002/chem.201404082
UR - https://doi.org/10.1002/chem.201404082
TI - Catalytic Formation of Acrylate from Carbon Dioxide and Ethene
T2 - Chemistry - A European Journal
AU - Hendriksen, Coen
AU - Pidko, Evgeny A.
AU - Yang, Gang
AU - Schäffner, Benjamin
AU - Vogt, Dieter
PY - 2014
DA - 2014/08/12
PB - Wiley
SP - 12037-12040
IS - 38
VL - 20
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex
Copy
@article{2014_Hendriksen,
author = {Coen Hendriksen and Evgeny A. Pidko and Gang Yang and Benjamin Schäffner and Dieter Vogt},
title = {Catalytic Formation of Acrylate from Carbon Dioxide and Ethene},
journal = {Chemistry - A European Journal},
year = {2014},
volume = {20},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/chem.201404082},
number = {38},
pages = {12037--12040},
doi = {10.1002/chem.201404082}
}
Cite this
MLA
Copy
Hendriksen, Coen, et al. “Catalytic Formation of Acrylate from Carbon Dioxide and Ethene.” Chemistry - A European Journal, vol. 20, no. 38, Aug. 2014, pp. 12037-12040. https://doi.org/10.1002/chem.201404082.