, volume 20 , issue 44 , pages 14488-14492

Gallium-Assisted Transfer Hydrogenation of Alkenes

Bastien Michelet ¹

Christophe Bour ¹

Vincent Gandon ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Université Paris‐Sud, ICMMO (UMR CNRS 8182), LabEx CHARMAAAT, 91405 Orsay cedex (France), Fax: (+ 33)169154747, Homepage: www.polycata.u‐psud.fr |

Publication type: Journal Article

Publication date: 2014-09-11

Wiley

Chemistry - A European Journal

scimago Q1

wos Q2

SJR: 0.981

CiteScore: 6.7

Impact factor: 3.7

ISSN: 09476539, 15213765

DOI: 10.1002/chem.201404139

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PubMed ID: 25213294

General Chemistry

Catalysis

Organic Chemistry

Abstract

We report a rare case of alkene transfer hydrogenation using a main-group compound instead of a transition-metal complex as catalyst. We disclosed that 1,4-cyclohexadiene can be used as H2 surrogate towards olefin reduction in the presence of [IPrGaCl2 ][SbF6 ]. Hydrogenative cyclizations have also been carried out because this cationic gallium complex is also a potent hydroarylation catalyst.

Found

1 citation

Mikhaylov Vladimir

PhD in Chemistry

20 publications, 381 citations

h-index: 11

Saint Petersburg State University

Research interests

Catalysis

1 citation

Novikov Maxim

🥼 🤝

PhD in Chemistry

26 publications, 723 citations

h-index: 9

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

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Michelet B., Bour C., Gandon V. Gallium-Assisted Transfer Hydrogenation of Alkenes // Chemistry - A European Journal. 2014. Vol. 20. No. 44. pp. 14488-14492.

GOST all authors (up to 50) Copy

Michelet B., Bour C., Gandon V. Gallium-Assisted Transfer Hydrogenation of Alkenes // Chemistry - A European Journal. 2014. Vol. 20. No. 44. pp. 14488-14492.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/chem.201404139

UR - https://doi.org/10.1002/chem.201404139

TI - Gallium-Assisted Transfer Hydrogenation of Alkenes

T2 - Chemistry - A European Journal

AU - Michelet, Bastien

AU - Bour, Christophe

AU - Gandon, Vincent

PY - 2014

DA - 2014/09/11

PB - Wiley

SP - 14488-14492

IS - 44

VL - 20

PMID - 25213294

SN - 0947-6539

SN - 1521-3765

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2014_Michelet,

author = {Bastien Michelet and Christophe Bour and Vincent Gandon},

title = {Gallium-Assisted Transfer Hydrogenation of Alkenes},

journal = {Chemistry - A European Journal},

year = {2014},

volume = {20},

publisher = {Wiley},

month = {sep},

url = {https://doi.org/10.1002/chem.201404139},

number = {44},

pages = {14488--14492},

doi = {10.1002/chem.201404139}

}

MLA

Cite this

MLA Copy

Michelet, Bastien, et al. “Gallium-Assisted Transfer Hydrogenation of Alkenes.” Chemistry - A European Journal, vol. 20, no. 44, Sep. 2014, pp. 14488-14492. https://doi.org/10.1002/chem.201404139.

Publisher

Wiley

Journal

Chemistry - A European Journal

scimago Q1

wos Q2

SJR

0.981

CiteScore

6.7

Impact factor

3.7

ISSN

09476539 (Print)

15213765 (Electronic)