A Simple Iridicycle Catalyst for Efficient Transfer Hydrogenation of N-Heterocycles in Water
Publication type: Journal Article
Publication date: 2015-02-26
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
25728294
General Chemistry
Catalysis
Organic Chemistry
Abstract
A cyclometalated iridium complex is shown to catalyse the transfer hydrogenation of various nitrogen heterocycles, including but not limited to quinolines, isoquinolines, indoles and pyridinium salts, in an aqueous solution of HCO2H/HCO2Na under mild conditions. The catalyst shows excellent functional-group compatibility and high turnover number (up to 7500), with catalyst loadings as low as 0.01 mol % being feasible. Mechanistic investigation of the quinoline reduction suggests that the transfer hydrogenation proceeds via both 1,2- and 1,4-addition pathways, with the catalytic turnover being limited by the step of hydride transfer.
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Metrics
76
Total citations:
76
Citations from 2024:
5
(6.58%)
Cite this
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MLA
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GOST
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Talwar D. et al. A Simple Iridicycle Catalyst for Efficient Transfer Hydrogenation of N-Heterocycles in Water // Chemistry - A European Journal. 2015. Vol. 21. No. 14. pp. 5370-5379.
GOST all authors (up to 50)
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Talwar D., Li H. Y., Durham E., Xiao J. A Simple Iridicycle Catalyst for Efficient Transfer Hydrogenation of N-Heterocycles in Water // Chemistry - A European Journal. 2015. Vol. 21. No. 14. pp. 5370-5379.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201500016
UR - https://doi.org/10.1002/chem.201500016
TI - A Simple Iridicycle Catalyst for Efficient Transfer Hydrogenation of N-Heterocycles in Water
T2 - Chemistry - A European Journal
AU - Talwar, Dinesh
AU - Li, Ho Yin
AU - Durham, Emma
AU - Xiao, Jianliang
PY - 2015
DA - 2015/02/26
PB - Wiley
SP - 5370-5379
IS - 14
VL - 21
PMID - 25728294
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Talwar,
author = {Dinesh Talwar and Ho Yin Li and Emma Durham and Jianliang Xiao},
title = {A Simple Iridicycle Catalyst for Efficient Transfer Hydrogenation of N-Heterocycles in Water},
journal = {Chemistry - A European Journal},
year = {2015},
volume = {21},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/chem.201500016},
number = {14},
pages = {5370--5379},
doi = {10.1002/chem.201500016}
}
Cite this
MLA
Copy
Talwar, Dinesh, et al. “A Simple Iridicycle Catalyst for Efficient Transfer Hydrogenation of N-Heterocycles in Water.” Chemistry - A European Journal, vol. 21, no. 14, Feb. 2015, pp. 5370-5379. https://doi.org/10.1002/chem.201500016.