Mechanochromic Luminescence of Copper Iodide Clusters
Quentin Benito
1
,
I Maurin
1
,
Thibault Cheisson
2
,
G. Nocton
2
,
Alexandre Fargues
3
,
Alain Garcia
3
,
Charlotte Martineau
4
,
Thierry Gacoin
1
,
Jean-Pierre Boilot
1
,
1
Laboratoire de Physique de la Matière Condensée, UMR 7643, CNRS-Ecole Polytechnique 91128 Palaiseau Cedex, France
|
2
Laboratoire de Chimie Moléculaire LCM, UMR 9168 CNRS/École Polytechnique,91128 Palaiseau Cedex,France
|
Publication type: Journal Article
Publication date: 2015-03-05
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
25755012
General Chemistry
Catalysis
Organic Chemistry
Abstract
Luminescent mechanochromic materials are particularly appealing for the development of stimuli-responsive materials. Establishing the mechanism responsible for the mechanochromism is always an issue owing to the difficulty in characterizing the ground phase. Herein, the study of real crystalline polymorphs of a mechanochromic and thermochromic luminescent copper iodide cluster permits us to clearly establish the mechanism involved. The local disruption of the crystal packing induces changes in the cluster geometry and in particular the modification of the cuprophilic interactions, which consequently modify the emissive states. This study constitutes a step further toward the understanding of the mechanism involved in the mechanochromic luminescent properties of multimetallic coordination complexes.
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64
Total citations:
64
Citations from 2025:
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(10.94%)
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GOST
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Benito Q. et al. Mechanochromic Luminescence of Copper Iodide Clusters // Chemistry - A European Journal. 2015. Vol. 21. No. 15. pp. 5892-5897.
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Benito Q., Maurin I., Cheisson T., Nocton G., Fargues A., Garcia A., Martineau C., Gacoin T., Boilot J., Perruchas S. Mechanochromic Luminescence of Copper Iodide Clusters // Chemistry - A European Journal. 2015. Vol. 21. No. 15. pp. 5892-5897.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201500251
UR - https://doi.org/10.1002/chem.201500251
TI - Mechanochromic Luminescence of Copper Iodide Clusters
T2 - Chemistry - A European Journal
AU - Benito, Quentin
AU - Maurin, I
AU - Cheisson, Thibault
AU - Nocton, G.
AU - Fargues, Alexandre
AU - Garcia, Alain
AU - Martineau, Charlotte
AU - Gacoin, Thierry
AU - Boilot, Jean-Pierre
AU - Perruchas, Sandrine
PY - 2015
DA - 2015/03/05
PB - Wiley
SP - 5892-5897
IS - 15
VL - 21
PMID - 25755012
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Benito,
author = {Quentin Benito and I Maurin and Thibault Cheisson and G. Nocton and Alexandre Fargues and Alain Garcia and Charlotte Martineau and Thierry Gacoin and Jean-Pierre Boilot and Sandrine Perruchas},
title = {Mechanochromic Luminescence of Copper Iodide Clusters},
journal = {Chemistry - A European Journal},
year = {2015},
volume = {21},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/chem.201500251},
number = {15},
pages = {5892--5897},
doi = {10.1002/chem.201500251}
}
Cite this
MLA
Copy
Benito, Quentin, et al. “Mechanochromic Luminescence of Copper Iodide Clusters.” Chemistry - A European Journal, vol. 21, no. 15, Mar. 2015, pp. 5892-5897. https://doi.org/10.1002/chem.201500251.