Cobalt(III)-Catalyzed Dehydrative [4+2] Annulation of Oxime with Alkyne by CH and NOH Activation
Publication type: Journal Article
Publication date: 2015-09-25
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
26407181
General Chemistry
Catalysis
Organic Chemistry
Abstract
Efficient, scalable cobalt-catalyzed redox-neutral [4+2] annulation of readily available oximes and alkyne is reported. The developed synthetic methodology is widely applicable and tolerates various functional groups including heterocycles. A stable Cp*Co(III) neutral complex is employed as the catalyst for this redox-neutral [4+2] annulation reaction, which progresses smoothly by way of a reversible cyclometallation without any external oxidizing agent, and produces only water as the side product.
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Metrics
201
Total citations:
201
Citations from 2025:
7
(3.48%)
Cite this
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Cite this
GOST
Copy
Sen M., Kalsi D., Sundararaju B. Cobalt(III)-Catalyzed Dehydrative [4+2] Annulation of Oxime with Alkyne by CH and NOH Activation // Chemistry - A European Journal. 2015. Vol. 21. No. 44. pp. 15529-15533.
GOST all authors (up to 50)
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Sen M., Kalsi D., Sundararaju B. Cobalt(III)-Catalyzed Dehydrative [4+2] Annulation of Oxime with Alkyne by CH and NOH Activation // Chemistry - A European Journal. 2015. Vol. 21. No. 44. pp. 15529-15533.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201503643
UR - https://doi.org/10.1002/chem.201503643
TI - Cobalt(III)-Catalyzed Dehydrative [4+2] Annulation of Oxime with Alkyne by CH and NOH Activation
T2 - Chemistry - A European Journal
AU - Sen, Malay
AU - Kalsi, Deepti
AU - Sundararaju, Basker
PY - 2015
DA - 2015/09/25
PB - Wiley
SP - 15529-15533
IS - 44
VL - 21
PMID - 26407181
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Sen,
author = {Malay Sen and Deepti Kalsi and Basker Sundararaju},
title = {Cobalt(III)-Catalyzed Dehydrative [4+2] Annulation of Oxime with Alkyne by CH and NOH Activation},
journal = {Chemistry - A European Journal},
year = {2015},
volume = {21},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/chem.201503643},
number = {44},
pages = {15529--15533},
doi = {10.1002/chem.201503643}
}
Cite this
MLA
Copy
Sen, Malay, et al. “Cobalt(III)-Catalyzed Dehydrative [4+2] Annulation of Oxime with Alkyne by CH and NOH Activation.” Chemistry - A European Journal, vol. 21, no. 44, Sep. 2015, pp. 15529-15533. https://doi.org/10.1002/chem.201503643.