Chemistry - A European Journal

, volume 22 , issue 37 , pages 13059-13063

Visible-Light-Induced Trifluoromethylation of Isonitrile-Substituted Methylenecyclopropanes: Facile Access to 6-(Trifluoromethyl)-7,8-Dihydrobenzo[k]phenanthridine Derivatives

Yu Chao Yuan ¹

Hou Lu Liu ²

Xu Bo Hu ³

尹维 Wei Yin ¹

Min Shi ^{1, 3}

Hide authors affiliations Show authors affiliations: 3 affiliations

State Key Laboratory of Organometallic Chemistry; Shanghai Institute of Organic Chemistry; Chinese Academy of Sciences; 345 Lingling Road Shanghai 200032 P.R. China |

Department of Chemistry; Shanghai University; 99 Shangda Road Shanghai 200444 P.R. China |

Key Laboratory for Advanced Materials and Institute of Fine Chemicals; East China University of Science and Technology; Meilong Road No. 130 Shanghai 200237 P.R. China |

Publication type: Journal Article

Publication date: 2016-08-09

Wiley

Chemistry - A European Journal

scimago Q1

wos Q2

SJR: 0.981

CiteScore: 6.7

Impact factor: 3.7

ISSN: 09476539, 15213765

DOI: 10.1002/chem.201602920

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PubMed ID: 27433794

General Chemistry

Catalysis

Organic Chemistry

Abstract

A new visible-light-induced trifluoromethylation of isonitrile-substituted methylenecyclopropanes is developed. A range of substituted 6-(trifluoromethyl)-7,8-dihydrobenzo[k]phenanthridine derivatives are readily furnished by this newly developed tandem reaction with moderate to good yields. This reaction allows the direct formation of two six-membered rings and three new C-C bonds, including the C-CF3 bond, under visible light irradiation.

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Yuan Yu. C. et al. Visible-Light-Induced Trifluoromethylation of Isonitrile-Substituted Methylenecyclopropanes: Facile Access to 6-(Trifluoromethyl)-7,8-Dihydrobenzo[k]phenanthridine Derivatives // Chemistry - A European Journal. 2016. Vol. 22. No. 37. pp. 13059-13063.

GOST all authors (up to 50) Copy

Yuan Yu. C., Liu H. L., Hu X. B., Wei Yin 尹., Shi M. Visible-Light-Induced Trifluoromethylation of Isonitrile-Substituted Methylenecyclopropanes: Facile Access to 6-(Trifluoromethyl)-7,8-Dihydrobenzo[k]phenanthridine Derivatives // Chemistry - A European Journal. 2016. Vol. 22. No. 37. pp. 13059-13063.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/chem.201602920

UR - https://doi.org/10.1002/chem.201602920

TI - Visible-Light-Induced Trifluoromethylation of Isonitrile-Substituted Methylenecyclopropanes: Facile Access to 6-(Trifluoromethyl)-7,8-Dihydrobenzo[k]phenanthridine Derivatives

T2 - Chemistry - A European Journal

AU - Yuan, Yu Chao

AU - Liu, Hou Lu

AU - Hu, Xu Bo

AU - Wei Yin, 尹维

AU - Shi, Min

PY - 2016

DA - 2016/08/09

PB - Wiley

SP - 13059-13063

IS - 37

VL - 22

PMID - 27433794

SN - 0947-6539

SN - 1521-3765

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2016_Yuan,

author = {Yu Chao Yuan and Hou Lu Liu and Xu Bo Hu and 尹维 Wei Yin and Min Shi},

title = {Visible-Light-Induced Trifluoromethylation of Isonitrile-Substituted Methylenecyclopropanes: Facile Access to 6-(Trifluoromethyl)-7,8-Dihydrobenzo[k]phenanthridine Derivatives},

journal = {Chemistry - A European Journal},

year = {2016},

volume = {22},

publisher = {Wiley},

month = {aug},

url = {https://doi.org/10.1002/chem.201602920},

number = {37},

pages = {13059--13063},

doi = {10.1002/chem.201602920}

}

MLA

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MLA Copy

Yuan, Yu. Chao, et al. “Visible-Light-Induced Trifluoromethylation of Isonitrile-Substituted Methylenecyclopropanes: Facile Access to 6-(Trifluoromethyl)-7,8-Dihydrobenzo[k]phenanthridine Derivatives.” Chemistry - A European Journal, vol. 22, no. 37, Aug. 2016, pp. 13059-13063. https://doi.org/10.1002/chem.201602920.

Publisher

Wiley

Journal

Chemistry - A European Journal

scimago Q1

wos Q2

SJR

0.981

CiteScore

6.7

Impact factor

3.7

ISSN

09476539 (Print)

15213765 (Electronic)