Aggregation-Induced Emission and Sensing Characteristics of Triarylborane-Oligothiophene-Dicyanovinyl Triads
Publication type: Journal Article
Publication date: 2016-09-28
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
27678493
General Chemistry
Catalysis
Organic Chemistry
Abstract
The design, synthesis and aggregation-induced emission properties of a new series of triarylborane-oligothiophene-dicyanovinyl (DCV) conjugates 4-6 (A-D-A' type molecular configuration) are reported. The optical properties of 4-6 can be modulated by judiciously varying the number of thiophene units between electron deficient boryl and dicyanovinyl units. Compound 6 with terthiophene spacer showed highly red-shifted absorption and emission compared to 5 and 4 with bithiophene and monothiophene spacers, respectively. Compounds 5 and 6 show aggregation-induced emission enhancement in water/THF mixtures. Compounds 5 and 6 also showed solvent viscosity dependent emission characteristics. All the three compounds show distinct optical responses for small anions such as fluoride and cyanide. Filter paper strips coated with compounds 5 and 6 can detect F- and CN- in aqueous media with different colorimetric responses.
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Kumar G. R., Sarkar S. K., Thilagar P. Aggregation-Induced Emission and Sensing Characteristics of Triarylborane-Oligothiophene-Dicyanovinyl Triads // Chemistry - A European Journal. 2016. Vol. 22. No. 48. pp. 17215-17225.
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Kumar G. R., Sarkar S. K., Thilagar P. Aggregation-Induced Emission and Sensing Characteristics of Triarylborane-Oligothiophene-Dicyanovinyl Triads // Chemistry - A European Journal. 2016. Vol. 22. No. 48. pp. 17215-17225.
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TY - JOUR
DO - 10.1002/chem.201603349
UR - https://doi.org/10.1002/chem.201603349
TI - Aggregation-Induced Emission and Sensing Characteristics of Triarylborane-Oligothiophene-Dicyanovinyl Triads
T2 - Chemistry - A European Journal
AU - Kumar, George Rajendra
AU - Sarkar, Samir K.
AU - Thilagar, Ponsindhu
PY - 2016
DA - 2016/09/28
PB - Wiley
SP - 17215-17225
IS - 48
VL - 22
PMID - 27678493
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2016_Kumar,
author = {George Rajendra Kumar and Samir K. Sarkar and Ponsindhu Thilagar},
title = {Aggregation-Induced Emission and Sensing Characteristics of Triarylborane-Oligothiophene-Dicyanovinyl Triads},
journal = {Chemistry - A European Journal},
year = {2016},
volume = {22},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/chem.201603349},
number = {48},
pages = {17215--17225},
doi = {10.1002/chem.201603349}
}
Cite this
MLA
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Kumar, George Rajendra, et al. “Aggregation-Induced Emission and Sensing Characteristics of Triarylborane-Oligothiophene-Dicyanovinyl Triads.” Chemistry - A European Journal, vol. 22, no. 48, Sep. 2016, pp. 17215-17225. https://doi.org/10.1002/chem.201603349.