Chemistry - A European Journal, volume 23, issue 59, pages 14944-14953
Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree
Kalyakina Alena S
1, 2
,
Utochnikova Valentina
2, 3
,
Volz Daniel
5
,
Weis Patrick
6
,
Schepers U.
7
,
Bräse Stefan
1, 7
5
Cynora GmbH; Werner-von-Siemens-Straße 2-6 76646 Bruchsal Germany
|
Publication type: Journal Article
Publication date: 2017-09-22
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
The thorough study of fluorinated benzoates of lanthanides (Eu, Tb, Nd, Er, Yb, Gd, La, Lu) is reported. Their composition in single crystal and powder state revealed two predominant structural motifs. An in-depth luminescence study has been performed on the reported fluorobenzoates, showing, that terbium and europium complexes in solid state possess high luminescence intensity with the quantum yield of up to 69 %. High solubility in most organic solvents, as well as in water, combined with the high luminescence intensity in water solution and non-toxicity allowed the testing of europium complexes as bioprobes in cellulo. Among all tested fluorobenzoates, europium 2-fluorobenzoate dihydrate combined the best luminescent properties, thermodynamic stability, aqueous solubility, and non-toxicity, and was shown to be a viable bio-marker.
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Citations by publishers
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Wiley
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1 publication, 4.17%
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1 publication, 4.17%
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1 publication, 4.17%
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Springer Nature
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Springer Nature
1 publication, 4.17%
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1
2
3
4
5
6
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8
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kalyakina A. S. et al. Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree // Chemistry - A European Journal. 2017. Vol. 23. No. 59. pp. 14944-14953.
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Kalyakina A. S., Utochnikova V., Bushmarinov I. S., Le Deygen I. M., Volz D., Weis P., Schepers U., Kuzmina N. P., Bräse S. Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree // Chemistry - A European Journal. 2017. Vol. 23. No. 59. pp. 14944-14953.
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TY - JOUR
DO - 10.1002/chem.201703543
UR - https://doi.org/10.1002%2Fchem.201703543
TI - Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree
T2 - Chemistry - A European Journal
AU - Volz, Daniel
AU - Kalyakina, Alena S
AU - Utochnikova, Valentina
AU - Bushmarinov, I. S.
AU - Le Deygen, Irina M
AU - Schepers, U.
AU - Kuzmina, Natalia P.
AU - Bräse, Stefan
AU - Weis, Patrick
PY - 2017
DA - 2017/09/22 00:00:00
PB - Wiley
SP - 14944-14953
IS - 59
VL - 23
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2017_Kalyakina,
author = {Daniel Volz and Alena S Kalyakina and Valentina Utochnikova and I. S. Bushmarinov and Irina M Le Deygen and U. Schepers and Natalia P. Kuzmina and Stefan Bräse and Patrick Weis},
title = {Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree},
journal = {Chemistry - A European Journal},
year = {2017},
volume = {23},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002%2Fchem.201703543},
number = {59},
pages = {14944--14953},
doi = {10.1002/chem.201703543}
}
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MLA
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Kalyakina, Alena S., et al. “Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree.” Chemistry - A European Journal, vol. 23, no. 59, Sep. 2017, pp. 14944-14953. https://doi.org/10.1002%2Fchem.201703543.