Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree
Alena S Kalyakina
1, 2
,
Valentina Utochnikova
2, 3
,
Daniel Volz
5
,
Patrick Weis
6
,
U. Schepers
7
,
Stefan Bräse
1, 7
Publication type: Journal Article
Publication date: 2017-09-22
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
28833886
General Chemistry
Catalysis
Organic Chemistry
Abstract
The thorough study of fluorinated benzoates of lanthanides (Eu, Tb, Nd, Er, Yb, Gd, La, Lu) is reported. Their composition in single crystal and powder state revealed two predominant structural motifs. An in-depth luminescence study has been performed on the reported fluorobenzoates, showing, that terbium and europium complexes in solid state possess high luminescence intensity with the quantum yield of up to 69 %. High solubility in most organic solvents, as well as in water, combined with the high luminescence intensity in water solution and non-toxicity allowed the testing of europium complexes as bioprobes in cellulo. Among all tested fluorobenzoates, europium 2-fluorobenzoate dihydrate combined the best luminescent properties, thermodynamic stability, aqueous solubility, and non-toxicity, and was shown to be a viable bio-marker.
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Total citations:
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Citations from 2024:
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GOST
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Kalyakina A. S. et al. Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree // Chemistry - A European Journal. 2017. Vol. 23. No. 59. pp. 14944-14953.
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Kalyakina A. S., Utochnikova V., Bushmarinov I. S., Le Deygen I. M., Volz D., Weis P., Schepers U., Kuzmina N. P., Bräse S. Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree // Chemistry - A European Journal. 2017. Vol. 23. No. 59. pp. 14944-14953.
Cite this
RIS
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TY - JOUR
DO - 10.1002/chem.201703543
UR - https://doi.org/10.1002/chem.201703543
TI - Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree
T2 - Chemistry - A European Journal
AU - Kalyakina, Alena S
AU - Utochnikova, Valentina
AU - Bushmarinov, I. S.
AU - Le Deygen, Irina M
AU - Volz, Daniel
AU - Weis, Patrick
AU - Schepers, U.
AU - Kuzmina, Natalia P.
AU - Bräse, Stefan
PY - 2017
DA - 2017/09/22
PB - Wiley
SP - 14944-14953
IS - 59
VL - 23
PMID - 28833886
SN - 0947-6539
SN - 1521-3765
ER -
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BibTex (up to 50 authors)
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@article{2017_Kalyakina,
author = {Alena S Kalyakina and Valentina Utochnikova and I. S. Bushmarinov and Irina M Le Deygen and Daniel Volz and Patrick Weis and U. Schepers and Natalia P. Kuzmina and Stefan Bräse},
title = {Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree},
journal = {Chemistry - A European Journal},
year = {2017},
volume = {23},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/chem.201703543},
number = {59},
pages = {14944--14953},
doi = {10.1002/chem.201703543}
}
Cite this
MLA
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Kalyakina, Alena S., et al. “Lanthanide Fluorobenzoates as Bio-Probes: a Quest for the Optimal Ligand Fluorination Degree.” Chemistry - A European Journal, vol. 23, no. 59, Sep. 2017, pp. 14944-14953. https://doi.org/10.1002/chem.201703543.