Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer
Stanislav I. Bezzubov
1, 2
,
Paulina Kalle
1, 2
,
Alfiya A. Bilyalova
3, 4
,
Vladimir D. Dolzhenko
3, 4
3
Publication type: Journal Article
Publication date: 2018-08-01
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
29939438
General Chemistry
Catalysis
Organic Chemistry
Abstract
Iridium(III) is often considered to be one of the most inert octahedral metal ions. Herein we present a phenanthroimidazole‐based bis‐cyclometalated iridium(III) chloride undergoing a facile chloro ligand exchange with iodine, in a gas‐solid reaction under ambient conditions. Monitoring the progress of the reaction by X‐ray diffraction analysis reveals the crystal‐packing‐induced exceptional stereoselectivity of this topochemical transformation. The results provide excellent opportunities to modulate the geometry and kinetic properties of cyclometalated iridium(III) complexes that may be very promising in catalysis and design of anticancer agents.
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Total citations:
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Citations from 2024:
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(29%)
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GOST
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Bezzubov S. I. et al. Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer // Chemistry - A European Journal. 2018. Vol. 24. No. 49. pp. 12779-12783.
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Bezzubov S. I., Kalle P., Bilyalova A. A., Tatarin S. V., Dolzhenko V. D. Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer // Chemistry - A European Journal. 2018. Vol. 24. No. 49. pp. 12779-12783.
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RIS
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TY - JOUR
DO - 10.1002/chem.201801963
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201801963
TI - Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer
T2 - Chemistry - A European Journal
AU - Bezzubov, Stanislav I.
AU - Kalle, Paulina
AU - Bilyalova, Alfiya A.
AU - Tatarin, Sergei V.
AU - Dolzhenko, Vladimir D.
PY - 2018
DA - 2018/08/01
PB - Wiley
SP - 12779-12783
IS - 49
VL - 24
PMID - 29939438
SN - 0947-6539
SN - 1521-3765
ER -
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BibTex (up to 50 authors)
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@article{2018_Bezzubov,
author = {Stanislav I. Bezzubov and Paulina Kalle and Alfiya A. Bilyalova and Sergei V. Tatarin and Vladimir D. Dolzhenko},
title = {Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer},
journal = {Chemistry - A European Journal},
year = {2018},
volume = {24},
publisher = {Wiley},
month = {aug},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201801963},
number = {49},
pages = {12779--12783},
doi = {10.1002/chem.201801963}
}
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MLA
Copy
Bezzubov, Stanislav I., et al. “Overcoming the Inertness of Iridium(III) in a Facile Single‐Crystal to Single‐Crystal Reaction of Iodine Vapor with a Cyclometalated Chloride Monomer.” Chemistry - A European Journal, vol. 24, no. 49, Aug. 2018, pp. 12779-12783. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201801963.