A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks
Sergey A Adonin
1, 2
,
Liubov I Udalova
1, 2
,
Pavel A. Abramov
1, 2
,
Irina V Yushina
1
,
I. Korolkov
1, 2
,
Evgeniy Y Semitut
1
,
Tatiyana A Derzhavskaya
4
,
Pavel A. Troshin
4, 5
,
Maxim Sokolov
1, 2
,
Vladimir P. Fedin
1, 2
Publication type: Journal Article
Publication date: 2018-09-06
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
30020549
General Chemistry
Catalysis
Organic Chemistry
Abstract
In the presence of different cations, reactions of [SbBr6 ]3- and I2 result in a new family of diverse supramolecular 1D polyiodide-bromoantimonate networks. The coordination number of Sb, as well as geometry of assembling {Ix }n- polyhalide units, can vary, resulting in unprecedented structural types. The nature of I⋅⋅⋅Br interactions was studied by DFT calculations; estimated energy values are 1.6-6.9 kcal mol-1 . Some of the compounds showed strong photoconductivity in thin films, suggesting multiple feasible applications in optoelectronics and solar energy conversion.
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71
Total citations:
71
Citations from 2024:
15
(21%)
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GOST
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Adonin S. A. et al. A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks // Chemistry - A European Journal. 2018. Vol. 24. No. 55. pp. 14707-14711.
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Adonin S. A., Udalova L. I., Abramov P. A., Novikov A. S., Yushina I. V., Korolkov I., Semitut E. Y., Derzhavskaya T. A., Stevenson K. J., Troshin P. A., Sokolov M., Fedin V. P. A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks // Chemistry - A European Journal. 2018. Vol. 24. No. 55. pp. 14707-14711.
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TY - JOUR
DO - 10.1002/chem.201802100
UR - https://doi.org/10.1002/chem.201802100
TI - A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks
T2 - Chemistry - A European Journal
AU - Adonin, Sergey A
AU - Udalova, Liubov I
AU - Abramov, Pavel A.
AU - Novikov, Alexander S.
AU - Yushina, Irina V
AU - Korolkov, I.
AU - Semitut, Evgeniy Y
AU - Derzhavskaya, Tatiyana A
AU - Stevenson, Keith J
AU - Troshin, Pavel A.
AU - Sokolov, Maxim
AU - Fedin, Vladimir P.
PY - 2018
DA - 2018/09/06
PB - Wiley
SP - 14707-14711
IS - 55
VL - 24
PMID - 30020549
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Adonin,
author = {Sergey A Adonin and Liubov I Udalova and Pavel A. Abramov and Alexander S. Novikov and Irina V Yushina and I. Korolkov and Evgeniy Y Semitut and Tatiyana A Derzhavskaya and Keith J Stevenson and Pavel A. Troshin and Maxim Sokolov and Vladimir P. Fedin},
title = {A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks},
journal = {Chemistry - A European Journal},
year = {2018},
volume = {24},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/chem.201802100},
number = {55},
pages = {14707--14711},
doi = {10.1002/chem.201802100}
}
Cite this
MLA
Copy
Adonin, Sergey A., et al. “A Novel Family of Polyiodo-Bromoantimonate(III) Complexes: Cation-Driven Self-Assembly of Photoconductive Metal-Polyhalide Frameworks.” Chemistry - A European Journal, vol. 24, no. 55, Sep. 2018, pp. 14707-14711. https://doi.org/10.1002/chem.201802100.