Donor-Acceptor Complexes between 1,2,5-Chalcogenadiazoles (Te, Se, S) and the Pseudohalides CN− and XCN− (X=O, S, Se, Te)
Nikolay Semenov
1
,
Dmitry Gorbunov
2, 3
,
Margarita V Shakhova
2, 3
,
Georgi E Salnikov
1, 4
,
Valery V Korolev
2
,
Jens Beckmann
5
,
N.P Gritsan
2, 3
,
Andrey V. Zibarev
1, 3, 6
5
Publication type: Journal Article
Publication date: 2018-07-27
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
29882626
General Chemistry
Catalysis
Organic Chemistry
Abstract
Donor-acceptor (D-A) complexes between 3,4-dicyano-1,2,5-chalcogenadiazoles [chalcogen=Te (1 a), Se (1 b), S (1 c)] and the pseudohalides CN- and XCN- (X=O, S, Se, Te) were studied experimentally and theoretically. For 1 a, they were isolated as [K(18-crown-6)][1 a-CN] (2), [K(18-crown-6)][1 a-NCO] (3), [K(18-crown-6)][1 a-SCN] (4), [K(18-crown-6)][1 a-SeCN] (5), and [K][1 a-NCSe] (6) and characterized by X-ray diffraction (XRD), UV/Vis and NMR spectroscopy, and DFT and QTAIM calculations. For 1 b and 1 c, the complexes were not isolated due to unfavorable thermodynamics. In all isolated complexes, the D-A bonds, stabilized by negative hyperconjugation, were longer than the sum of the covalent radii and shorter than the sum of the van der Waals radii of the bonded atoms. In mixtures of 1 a, F- , and SeCN- , the complex [1 a-F]- was selectively formed in accordance with thermodynamics. The reaction of 1 a with SeCN- and the cyclic trimeric perfluoro-ortho-phenylene mercury afforded the complex [K(18-crown-6)][SCN]⋅(o-C6 F4 Hg)3 , which was characterized by XRD.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
|
|
|
Coordination Chemistry Reviews
4 publications, 8.7%
|
|
|
Angewandte Chemie
3 publications, 6.52%
|
|
|
Angewandte Chemie - International Edition
3 publications, 6.52%
|
|
|
Crystal Growth and Design
3 publications, 6.52%
|
|
|
Chemistry - A European Journal
2 publications, 4.35%
|
|
|
Molecules
2 publications, 4.35%
|
|
|
Chemical Physics
2 publications, 4.35%
|
|
|
Mendeleev Communications
2 publications, 4.35%
|
|
|
ChemistrySelect
2 publications, 4.35%
|
|
|
Organometallics
2 publications, 4.35%
|
|
|
Journal of Physical Chemistry A
2 publications, 4.35%
|
|
|
CrystEngComm
2 publications, 4.35%
|
|
|
Asian Journal of Organic Chemistry
1 publication, 2.17%
|
|
|
Chemical Communications
1 publication, 2.17%
|
|
|
Journal of Molecular Modeling
1 publication, 2.17%
|
|
|
Russian Chemical Bulletin
1 publication, 2.17%
|
|
|
Journal of Photochemistry and Photobiology A: Chemistry
1 publication, 2.17%
|
|
|
Polyhedron
1 publication, 2.17%
|
|
|
European Journal of Inorganic Chemistry
1 publication, 2.17%
|
|
|
Applied Organometallic Chemistry
1 publication, 2.17%
|
|
|
ChemPhysChem
1 publication, 2.17%
|
|
|
New Journal of Chemistry
1 publication, 2.17%
|
|
|
ChemPlusChem
1 publication, 2.17%
|
|
|
Electrochemical Energy Reviews
1 publication, 2.17%
|
|
|
RSC Mechanochemistry
1 publication, 2.17%
|
|
|
Journal of Chemical Sciences
1 publication, 2.17%
|
|
|
1
2
3
4
|
Publishers
|
2
4
6
8
10
12
14
16
|
|
|
Wiley
15 publications, 32.61%
|
|
|
Elsevier
11 publications, 23.91%
|
|
|
American Chemical Society (ACS)
7 publications, 15.22%
|
|
|
Royal Society of Chemistry (RSC)
5 publications, 10.87%
|
|
|
Springer Nature
4 publications, 8.7%
|
|
|
MDPI
2 publications, 4.35%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
2 publications, 4.35%
|
|
|
2
4
6
8
10
12
14
16
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
46
Total citations:
46
Citations from 2025:
3
(6.52%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Semenov N. et al. Donor-Acceptor Complexes between 1,2,5-Chalcogenadiazoles (Te, Se, S) and the Pseudohalides CN− and XCN− (X=O, S, Se, Te) // Chemistry - A European Journal. 2018. Vol. 24. No. 49. pp. 12983-12991.
GOST all authors (up to 50)
Copy
Semenov N., Gorbunov D., Shakhova M. V., Salnikov G. E., Bagryanskaya I. Y., Korolev V. V., Beckmann J., Gritsan N., Zibarev A. V. Donor-Acceptor Complexes between 1,2,5-Chalcogenadiazoles (Te, Se, S) and the Pseudohalides CN− and XCN− (X=O, S, Se, Te) // Chemistry - A European Journal. 2018. Vol. 24. No. 49. pp. 12983-12991.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/chem.201802257
UR - https://doi.org/10.1002/chem.201802257
TI - Donor-Acceptor Complexes between 1,2,5-Chalcogenadiazoles (Te, Se, S) and the Pseudohalides CN− and XCN− (X=O, S, Se, Te)
T2 - Chemistry - A European Journal
AU - Semenov, Nikolay
AU - Gorbunov, Dmitry
AU - Shakhova, Margarita V
AU - Salnikov, Georgi E
AU - Bagryanskaya, Irina Yu.
AU - Korolev, Valery V
AU - Beckmann, Jens
AU - Gritsan, N.P
AU - Zibarev, Andrey V.
PY - 2018
DA - 2018/07/27
PB - Wiley
SP - 12983-12991
IS - 49
VL - 24
PMID - 29882626
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Semenov,
author = {Nikolay Semenov and Dmitry Gorbunov and Margarita V Shakhova and Georgi E Salnikov and Irina Yu. Bagryanskaya and Valery V Korolev and Jens Beckmann and N.P Gritsan and Andrey V. Zibarev},
title = {Donor-Acceptor Complexes between 1,2,5-Chalcogenadiazoles (Te, Se, S) and the Pseudohalides CN− and XCN− (X=O, S, Se, Te)},
journal = {Chemistry - A European Journal},
year = {2018},
volume = {24},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/chem.201802257},
number = {49},
pages = {12983--12991},
doi = {10.1002/chem.201802257}
}
Cite this
MLA
Copy
Semenov, Nikolay, et al. “Donor-Acceptor Complexes between 1,2,5-Chalcogenadiazoles (Te, Se, S) and the Pseudohalides CN− and XCN− (X=O, S, Se, Te).” Chemistry - A European Journal, vol. 24, no. 49, Jul. 2018, pp. 12983-12991. https://doi.org/10.1002/chem.201802257.