Chemistry - A European Journal, volume 25, issue 29, pages 7142-7148
Building a Cocrystal by Using Supramolecular Synthons for Pressure‐Accelerated Heteromolecular Azide–Alkyne Cycloaddition
2
Department of Chemistry and PhysicsSalem State University 352 Lafayette Street Salem MA 01970 USA
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Publication type: Journal Article
Publication date: 2019-04-11
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
SJR: 1.058
CiteScore: 7.9
Impact factor: 3.9
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
Facilitated by the supramolecular synthons of carboxylic acids and amides through cooperative hydrogen-bonding and arene-perfluoroarene interactions, the azide-alkyne cycloaddition reaction between two different molecules in a cocrystal was achieved. This reaction could be accelerated by pressure using a common hydraulic press equipment with excellent regioselectivity to yield 1,4-triazole products. The absence of decarboxylation side reactions in the products in the solid state demonstrated that this strategy can provide a green synthetic route for products not directly accessible by traditional syntheses in solution.
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Meng X. et al. Building a Cocrystal by Using Supramolecular Synthons for Pressure‐Accelerated Heteromolecular Azide–Alkyne Cycloaddition // Chemistry - A European Journal. 2019. Vol. 25. No. 29. pp. 7142-7148.
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Meng X., CHEN C., Deng X., Wang Z., Chen Q., Ma Y. Building a Cocrystal by Using Supramolecular Synthons for Pressure‐Accelerated Heteromolecular Azide–Alkyne Cycloaddition // Chemistry - A European Journal. 2019. Vol. 25. No. 29. pp. 7142-7148.
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TY - JOUR
DO - 10.1002/chem.201900391
UR - https://doi.org/10.1002/chem.201900391
TI - Building a Cocrystal by Using Supramolecular Synthons for Pressure‐Accelerated Heteromolecular Azide–Alkyne Cycloaddition
T2 - Chemistry - A European Journal
AU - Meng, Xiao
AU - Deng, Xinyuan
AU - Wang, Zhangyuan
AU - Ma, Yuguo
AU - CHEN, CHANGQING
AU - Chen, Qi
PY - 2019
DA - 2019/04/11
PB - Wiley
SP - 7142-7148
IS - 29
VL - 25
SN - 0947-6539
SN - 1521-3765
ER -
Cite this
BibTex
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@article{2019_Meng,
author = {Xiao Meng and Xinyuan Deng and Zhangyuan Wang and Yuguo Ma and CHANGQING CHEN and Qi Chen},
title = {Building a Cocrystal by Using Supramolecular Synthons for Pressure‐Accelerated Heteromolecular Azide–Alkyne Cycloaddition},
journal = {Chemistry - A European Journal},
year = {2019},
volume = {25},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/chem.201900391},
number = {29},
pages = {7142--7148},
doi = {10.1002/chem.201900391}
}
Cite this
MLA
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Meng, Xiao, et al. “Building a Cocrystal by Using Supramolecular Synthons for Pressure‐Accelerated Heteromolecular Azide–Alkyne Cycloaddition.” Chemistry - A European Journal, vol. 25, no. 29, Apr. 2019, pp. 7142-7148. https://doi.org/10.1002/chem.201900391.