Chemistry - A European Journal, volume 25, issue 59, pages 13504-13508

Development of N ‐Phosphinomethyl‐Substituted NHC‐Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO 2

Publication typeJournal Article
Publication date2019-09-24
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor4.3
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
Nickel complexes with an N-phosphinomethyl-N-heterocyclic carbene ligand (NHC-P) have enhanced reducing ability and thermal stability and acrylate salt was prepared from ethylene and CO2 with the highest TON ever reported for nickel systems even without metallic zinc. Oxidative cyclization of ethylene and CO2 on the complex was found to proceed very rapidly.

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GOST |
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GOST Copy
Takahashi K. et al. Development of N ‐Phosphinomethyl‐Substituted NHC‐Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO 2 // Chemistry - A European Journal. 2019. Vol. 25. No. 59. pp. 13504-13508.
GOST all authors (up to 50) Copy
Takahashi K., Cho K., Iwai A., Ito T., Iwasawa N. Development of N ‐Phosphinomethyl‐Substituted NHC‐Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO 2 // Chemistry - A European Journal. 2019. Vol. 25. No. 59. pp. 13504-13508.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/chem.201903625
UR - https://doi.org/10.1002/chem.201903625
TI - Development of N ‐Phosphinomethyl‐Substituted NHC‐Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO 2
T2 - Chemistry - A European Journal
AU - Takahashi, Kohei
AU - Cho, Kinryo
AU - Iwai, Asaki
AU - Ito, Tatsuyoshi
AU - Iwasawa, N.
PY - 2019
DA - 2019/09/24
PB - Wiley
SP - 13504-13508
IS - 59
VL - 25
SN - 0947-6539
SN - 1521-3765
ER -
BibTex |
Cite this
BibTex Copy
@article{2019_Takahashi,
author = {Kohei Takahashi and Kinryo Cho and Asaki Iwai and Tatsuyoshi Ito and N. Iwasawa},
title = {Development of N ‐Phosphinomethyl‐Substituted NHC‐Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO 2},
journal = {Chemistry - A European Journal},
year = {2019},
volume = {25},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/chem.201903625},
number = {59},
pages = {13504--13508},
doi = {10.1002/chem.201903625}
}
MLA
Cite this
MLA Copy
Takahashi, Kohei, et al. “Development of N ‐Phosphinomethyl‐Substituted NHC‐Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO 2.” Chemistry - A European Journal, vol. 25, no. 59, Sep. 2019, pp. 13504-13508. https://doi.org/10.1002/chem.201903625.
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