Trivalent Rare‐Earth Metal Amide Complexes as Catalysts for the Hydrosilylation of Benzophenone Derivatives with HN(SiHMe 2 ) 2 by Amine‐Exchange Reaction
Publication type: Journal Article
Publication date: 2020-10-01
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
32634253
General Chemistry
Catalysis
Organic Chemistry
Abstract
The rare-earth metal complexes Ln(L1 )[N(SiHMe2 )2 ](thf) (Ln=La, Ce, Y; L1 =N,N''-bis(pentafluorophenyl)diethylenetriamine dianion) were synthesized by treating Ln[N(SiHMe2 )2 ]3 (thf)2 with L1 H2 . The lanthanum and cerium derivatives are active catalysts for the hydrosilylation of benzophenone derivatives with HN(SiHMe2 )2 . An amine-exchange reaction was revealed as a key step of the catalytic cycle, in which Ln-Si-H β-agostic interactions are proposed to promote insertion of the carbonyl moiety into the Si-H bond.
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Total citations:
9
Citations from 2025:
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(11.11%)
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Shinohara K. et al. Trivalent Rare‐Earth Metal Amide Complexes as Catalysts for the Hydrosilylation of Benzophenone Derivatives with HN(SiHMe 2 ) 2 by Amine‐Exchange Reaction // Chemistry - A European Journal. 2020. Vol. 26. No. 62. pp. 14130-14136.
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Shinohara K., Tsurugi H., Maichle-Mössmer C., Mashima K. Trivalent Rare‐Earth Metal Amide Complexes as Catalysts for the Hydrosilylation of Benzophenone Derivatives with HN(SiHMe 2 ) 2 by Amine‐Exchange Reaction // Chemistry - A European Journal. 2020. Vol. 26. No. 62. pp. 14130-14136.
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RIS
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TY - JOUR
DO - 10.1002/chem.202002011
UR - https://doi.org/10.1002/chem.202002011
TI - Trivalent Rare‐Earth Metal Amide Complexes as Catalysts for the Hydrosilylation of Benzophenone Derivatives with HN(SiHMe 2 ) 2 by Amine‐Exchange Reaction
T2 - Chemistry - A European Journal
AU - Shinohara, Koichi
AU - Tsurugi, Hayato
AU - Maichle-Mössmer, Cäcilia
AU - Mashima, Kazushi
PY - 2020
DA - 2020/10/01
PB - Wiley
SP - 14130-14136
IS - 62
VL - 26
PMID - 32634253
SN - 0947-6539
SN - 1521-3765
ER -
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BibTex (up to 50 authors)
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@article{2020_Shinohara,
author = {Koichi Shinohara and Hayato Tsurugi and Cäcilia Maichle-Mössmer and Kazushi Mashima},
title = {Trivalent Rare‐Earth Metal Amide Complexes as Catalysts for the Hydrosilylation of Benzophenone Derivatives with HN(SiHMe 2 ) 2 by Amine‐Exchange Reaction},
journal = {Chemistry - A European Journal},
year = {2020},
volume = {26},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/chem.202002011},
number = {62},
pages = {14130--14136},
doi = {10.1002/chem.202002011}
}
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MLA
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Shinohara, Koichi, et al. “Trivalent Rare‐Earth Metal Amide Complexes as Catalysts for the Hydrosilylation of Benzophenone Derivatives with HN(SiHMe 2 ) 2 by Amine‐Exchange Reaction.” Chemistry - A European Journal, vol. 26, no. 62, Oct. 2020, pp. 14130-14136. https://doi.org/10.1002/chem.202002011.