Chemistry - A European Journal

, volume 26 , issue 67 , pages 15346-15353

Electrophilic and Nucleophilic Aromatic Substitutions are Mechanistically Similar with Opposite Polarity

Mieczysław Mąkosza ¹

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Institute of Organic Chemistry Polish Academy of Sciences Kasprzaka 44/52 01–224 Warsaw 42 Poland |

Publication type: Journal Article

Publication date: 2020-11-11

Wiley

Chemistry - A European Journal

scimago Q1

wos Q2

SJR: 0.981

CiteScore: 6.7

Impact factor: 3.7

ISSN: 09476539, 15213765

DOI: 10.1002/chem.202003770

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PubMed ID: 33174247

General Chemistry

Catalysis

Organic Chemistry

Abstract

Confrontation of the recently formulated general mechanism of nucleophilic substitution in electron-deficient arenes with the well-known mechanism of electrophilic substitution revealed that these fundamental processes are mechanistically identical but proceed according to opposite polarity-an Umpolung relation. In this viewpoint this apparently controversial concept is supported by discussion of a variety of experimental results.

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Mąkosza M. Electrophilic and Nucleophilic Aromatic Substitutions are Mechanistically Similar with Opposite Polarity // Chemistry - A European Journal. 2020. Vol. 26. No. 67. pp. 15346-15353.

GOST all authors (up to 50) Copy

Mąkosza M. Electrophilic and Nucleophilic Aromatic Substitutions are Mechanistically Similar with Opposite Polarity // Chemistry - A European Journal. 2020. Vol. 26. No. 67. pp. 15346-15353.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/chem.202003770

UR - https://doi.org/10.1002/chem.202003770

TI - Electrophilic and Nucleophilic Aromatic Substitutions are Mechanistically Similar with Opposite Polarity

T2 - Chemistry - A European Journal

AU - Mąkosza, Mieczysław

PY - 2020

DA - 2020/11/11

PB - Wiley

SP - 15346-15353

IS - 67

VL - 26

PMID - 33174247

SN - 0947-6539

SN - 1521-3765

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2020_Mąkosza,

author = {Mieczysław Mąkosza},

title = {Electrophilic and Nucleophilic Aromatic Substitutions are Mechanistically Similar with Opposite Polarity},

journal = {Chemistry - A European Journal},

year = {2020},

volume = {26},

publisher = {Wiley},

month = {nov},

url = {https://doi.org/10.1002/chem.202003770},

number = {67},

pages = {15346--15353},

doi = {10.1002/chem.202003770}

}

MLA

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MLA Copy

Mąkosza, Mieczysław. “Electrophilic and Nucleophilic Aromatic Substitutions are Mechanistically Similar with Opposite Polarity.” Chemistry - A European Journal, vol. 26, no. 67, Nov. 2020, pp. 15346-15353. https://doi.org/10.1002/chem.202003770.

Publisher

Wiley

Journal

Chemistry - A European Journal

scimago Q1

wos Q2

SJR

0.981

CiteScore

6.7

Impact factor

3.7

ISSN

09476539 (Print)

15213765 (Electronic)