Wiley
Chemistry - A European Journal
,  volume 28 ,  issue 41

Intense Photoinduced Intervalence Charge Transfer in High‐Valent Iron Mixed Phenolate/Carbene Complexes

Alejandro Cadranel 1, 2, 3
, 
Lisa Gravogl 4
, 
D. Munz 4, 5
, 
K Meyer 4
1
 
2
 
3
 
4
 
5
 
Publication type: Journal Article
Publication date: 2022-06-13
Wiley
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
The usefulness of high-valent iron(NHC) chromophores is based on long-lived, ligand-to-metal charge transfer (LMCT) states. However, short-lived, metal-centered states may be populated if the ligands are not strong enough donors. We show that, thanks to metal-ligand covalency, iron ions can bridge ligand–ligand electronic communication, promoting ligand-based photoinduced intervalence charge transfer (PIIVCT) bands: spectroscopic markers in the usually silent NIR region that allow the interconversion between LMCT- and metal-centered states to be monitored.
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GOST Copy
Cadranel A. et al. Intense Photoinduced Intervalence Charge Transfer in High‐Valent Iron Mixed Phenolate/Carbene Complexes // Chemistry - A European Journal. 2022. Vol. 28. No. 41.
GOST all authors (up to 50) Copy
Cadranel A., Gravogl L., Munz D., Meyer K. Intense Photoinduced Intervalence Charge Transfer in High‐Valent Iron Mixed Phenolate/Carbene Complexes // Chemistry - A European Journal. 2022. Vol. 28. No. 41.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/chem.202200269
UR - https://doi.org/10.1002/chem.202200269
TI - Intense Photoinduced Intervalence Charge Transfer in High‐Valent Iron Mixed Phenolate/Carbene Complexes
T2 - Chemistry - A European Journal
AU - Cadranel, Alejandro
AU - Gravogl, Lisa
AU - Munz, D.
AU - Meyer, K
PY - 2022
DA - 2022/06/13
PB - Wiley
IS - 41
VL - 28
PMID - 35302682
SN - 0947-6539
SN - 1521-3765
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2022_Cadranel,
author = {Alejandro Cadranel and Lisa Gravogl and D. Munz and K Meyer},
title = {Intense Photoinduced Intervalence Charge Transfer in High‐Valent Iron Mixed Phenolate/Carbene Complexes},
journal = {Chemistry - A European Journal},
year = {2022},
volume = {28},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/chem.202200269},
number = {41},
doi = {10.1002/chem.202200269}
}