Chemistry - A European Journal
Iron‐Catalyzed Olefin Metathesis: Recent Theoretical and Experimental Advances
Publication type: Journal Article
Publication date: 2022-09-08
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
The "metathesis reaction" is a straightforward and often metal-catalyzed chemical reaction that transforms two hydrocarbon molecules to two new hydrocarbons by exchange of molecular fragments. Alkane, alkene and alkyne metathesis have become an important tool in synthetic chemistry and have provided access to complex organic structures. Since the discovery of industrial olefin metathesis in the 1960s, many modifications have been reported; thus, increasing scope and improving reaction selectivity. Olefin metathesis catalysts based on high-valent group six elements or Ru(IV) have been developed and improved through ligand modifications. In addition, significant effort was invested to realize olefin metathesis with a non-toxic, bio-compatible and one of the most abundant elements in the earth's crust; namely, iron. First evidences suggest that low-valent Fe(II) complexes are active in olefin metathesis. Although the latter has not been unambiguously established, this review summarizes the key advances in the field and aims to guide through the challenges.
Top-30
Citations by journals
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Angewandte Chemie
2 publications, 18.18%
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ACS Omega
1 publication, 9.09%
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Angewandte Chemie - International Edition
1 publication, 9.09%
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Organic and Biomolecular Chemistry
1 publication, 9.09%
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ACS Catalysis
1 publication, 9.09%
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Organometallics
1 publication, 9.09%
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European Journal of Inorganic Chemistry
1 publication, 9.09%
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Advanced Synthesis and Catalysis
1 publication, 9.09%
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Theoretical and Experimental Chemistry
1 publication, 9.09%
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Russian Chemical Reviews
1 publication, 9.09%
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Citations by publishers
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5
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Wiley
5 publications, 45.45%
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American Chemical Society (ACS)
3 publications, 27.27%
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Royal Society of Chemistry (RSC)
1 publication, 9.09%
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Springer Nature
1 publication, 9.09%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 9.09%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Grau B. W. et al. Iron‐Catalyzed Olefin Metathesis: Recent Theoretical and Experimental Advances // Chemistry - A European Journal. 2022.
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Grau B. W., Neuhauser A., Aghazada S., Meyer K., Tsogoeva S. B. Iron‐Catalyzed Olefin Metathesis: Recent Theoretical and Experimental Advances // Chemistry - A European Journal. 2022.
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TY - JOUR
DO - 10.1002/chem.202201414
UR - https://doi.org/10.1002/chem.202201414
TI - Iron‐Catalyzed Olefin Metathesis: Recent Theoretical and Experimental Advances
T2 - Chemistry - A European Journal
AU - Grau, Benedikt W
AU - Neuhauser, Alexander
AU - Aghazada, Sadig
AU - Meyer, K
AU - Tsogoeva, Svetlana B.
PY - 2022
DA - 2022/09/08 00:00:00
PB - Wiley
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2022_Grau,
author = {Benedikt W Grau and Alexander Neuhauser and Sadig Aghazada and K Meyer and Svetlana B. Tsogoeva},
title = {Iron‐Catalyzed Olefin Metathesis: Recent Theoretical and Experimental Advances},
journal = {Chemistry - A European Journal},
year = {2022},
publisher = {Wiley},
month = {sep},
url = {https://doi.org/10.1002/chem.202201414},
doi = {10.1002/chem.202201414}
}