Chemistry - A European Journal
Rhodium‐Catalyzed Acrylate Synthesis from Carbon Dioxide and Ethylene by using a Guanidine‐Based Pincer Ligand: Perturbing Occupied d‐Orbitals by pπ‐dπ Repulsion Makes a Difference
Publication type: Journal Article
Publication date: 2022-08-23
Journal:
Chemistry - A European Journal
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 4.3
ISSN: 09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Abstract
Rhodium-catalyzed acrylate synthesis from CO2 and ethylene was accomplished by using a guanidine-based NCN pincer ligand. The repulsion between pπ-electron of guanidine sidearms and occupied dπ orbital of rhodium center raised the level of d-electrons close to those of formerly known d8 -ruthenium catalyst, thereby promoting the metallalactone formation from carbon dioxide and ethylene. This work fills the absence of group-9 metal based catalyst for the acrylate synthesis and provides a designing approach for pincer-ligated d8 -metal catalysts to utilize pπ-dπ interaction for promoting desirable redox processes.
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Takegasa S. et al. Rhodium‐Catalyzed Acrylate Synthesis from Carbon Dioxide and Ethylene by using a Guanidine‐Based Pincer Ligand: Perturbing Occupied d‐Orbitals by pπ‐dπ Repulsion Makes a Difference // Chemistry - A European Journal. 2022.
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Takegasa S., Lee M., Tokuhiro K., Nakano R., Yamashita M. Rhodium‐Catalyzed Acrylate Synthesis from Carbon Dioxide and Ethylene by using a Guanidine‐Based Pincer Ligand: Perturbing Occupied d‐Orbitals by pπ‐dπ Repulsion Makes a Difference // Chemistry - A European Journal. 2022.
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TY - JOUR
DO - 10.1002/chem.202201870
UR - https://doi.org/10.1002/chem.202201870
TI - Rhodium‐Catalyzed Acrylate Synthesis from Carbon Dioxide and Ethylene by using a Guanidine‐Based Pincer Ligand: Perturbing Occupied d‐Orbitals by pπ‐dπ Repulsion Makes a Difference
T2 - Chemistry - A European Journal
AU - Takegasa, Shinnosuke
AU - Lee, Ming-Min
AU - Tokuhiro, Kei
AU - Nakano, Ryo
AU - Yamashita, Makoto
PY - 2022
DA - 2022/08/23
PB - Wiley
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2022_Takegasa,
author = {Shinnosuke Takegasa and Ming-Min Lee and Kei Tokuhiro and Ryo Nakano and Makoto Yamashita},
title = {Rhodium‐Catalyzed Acrylate Synthesis from Carbon Dioxide and Ethylene by using a Guanidine‐Based Pincer Ligand: Perturbing Occupied d‐Orbitals by pπ‐dπ Repulsion Makes a Difference},
journal = {Chemistry - A European Journal},
year = {2022},
publisher = {Wiley},
month = {aug},
url = {https://doi.org/10.1002/chem.202201870},
doi = {10.1002/chem.202201870}
}