Reactivity of Sodium Pentaphospholide Na[ cyclo ‐P 5 ] towards C≡E (E=C, N, P) Triple Bonds
Andrey Petrov
1
,
Lawrence Conrad
2
,
Nathan T Coles
1, 3
,
Manuela Weber
1
,
Dirk Andrae
2
,
Almaz Zagidullin
4
,
Vasili Miluykov
4
,
C. Muller
1
2
4
Publication type: Journal Article
Publication date: 2022-11-15
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
PubMed ID:
36210344
General Chemistry
Catalysis
Organic Chemistry
Abstract
A diglyme solution of Na[cyclo-P5] (1) reacts with alkynes and the isolobal nitriles and phosphaalkynes to afford the otherwise elusive (aza)phospholide anions 2a-c, 4a,b, and 6. The reaction of Na[cyclo-P5] with alkynes and nitriles was studied by means of DFT methods, which suggest a concerted mechanism for the formation of 2a and 4b. The anions 2a-c, 4a,b, and 6 coordinate in an η5-fashion towards Fe(II) to give the sandwich (aza)phosphametallocenes 3a-c, 5a,b and 7 in moderate to good yields. The new compounds were characterized by means of multinuclear NMR spectroscopy, single crystal X-ray diffraction and cyclic voltammetry.
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Total citations:
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Citations from 2024:
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(75%)
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Petrov A. et al. Reactivity of Sodium Pentaphospholide Na[ cyclo ‐P 5 ] towards C≡E (E=C, N, P) Triple Bonds // Chemistry - A European Journal. 2022. Vol. 28. No. 67.
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Petrov A., Conrad L., Coles N. T., Weber M., Andrae D., Zagidullin A., Miluykov V., Muller C. Reactivity of Sodium Pentaphospholide Na[ cyclo ‐P 5 ] towards C≡E (E=C, N, P) Triple Bonds // Chemistry - A European Journal. 2022. Vol. 28. No. 67.
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RIS
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TY - JOUR
DO - 10.1002/chem.202203056
UR - https://doi.org/10.1002/chem.202203056
TI - Reactivity of Sodium Pentaphospholide Na[ cyclo ‐P 5 ] towards C≡E (E=C, N, P) Triple Bonds
T2 - Chemistry - A European Journal
AU - Petrov, Andrey
AU - Conrad, Lawrence
AU - Coles, Nathan T
AU - Weber, Manuela
AU - Andrae, Dirk
AU - Zagidullin, Almaz
AU - Miluykov, Vasili
AU - Muller, C.
PY - 2022
DA - 2022/11/15
PB - Wiley
IS - 67
VL - 28
PMID - 36210344
SN - 0947-6539
SN - 1521-3765
ER -
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BibTex (up to 50 authors)
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@article{2022_Petrov,
author = {Andrey Petrov and Lawrence Conrad and Nathan T Coles and Manuela Weber and Dirk Andrae and Almaz Zagidullin and Vasili Miluykov and C. Muller},
title = {Reactivity of Sodium Pentaphospholide Na[ cyclo ‐P 5 ] towards C≡E (E=C, N, P) Triple Bonds},
journal = {Chemistry - A European Journal},
year = {2022},
volume = {28},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/chem.202203056},
number = {67},
doi = {10.1002/chem.202203056}
}
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