том 30 издание 3

Divergent and Nucleophile‐Assisted Rearrangement in the Construction of Pyrrolo[2,1‐b][3]benzazepine and Pyrido[2,1‐a]isoquinoline Scaffolds

Тип публикацииJournal Article
Дата публикации2023-11-20
scimago Q1
wos Q2
БС1
SJR0.981
CiteScore6.7
Impact factor3.7
ISSN09476539, 15213765
General Chemistry
Catalysis
Organic Chemistry
Краткое описание

Under microwave (MW) irradiation at 150 °C in toluene and in the presence of nucleophiles (DMAP, triphenylphosphine and tetrahydrothiophene) 1‐substituted 1‐ethynyl‐2‐vinyldi‐ and tetrahydroisoquinolines undergo [3,3]‐sigmatropic rearrangement providing pyrrolo[2,1‐b][3]benzazepines in good yields. The replacement of toluene with acetonitrile directs the rearrangement towards the formation of 7,11b‐dihydro‐6H‐pyrido[2,1‐a]isoquinolines.

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International Journal of Molecular Sciences
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Russian Chemical Reviews
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Tetrahedron
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Journal of Organic Chemistry
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Progress in Heterocyclic Chemistry
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Obydennik A. Y. et al. Divergent and Nucleophile‐Assisted Rearrangement in the Construction of Pyrrolo[2,1‐b][3]benzazepine and Pyrido[2,1‐a]isoquinoline Scaffolds // Chemistry - A European Journal. 2023. Vol. 30. No. 3.
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Obydennik A. Y., Titov A. A., Sbei N., Borisova T., Sokolova I. L., Rybakov V. B., Sharma N., Voskressensky L. G., Varlamov A. V. Divergent and Nucleophile‐Assisted Rearrangement in the Construction of Pyrrolo[2,1‐b][3]benzazepine and Pyrido[2,1‐a]isoquinoline Scaffolds // Chemistry - A European Journal. 2023. Vol. 30. No. 3.
RIS |
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TY - JOUR
DO - 10.1002/chem.202302919
UR - https://doi.org/10.1002/chem.202302919
TI - Divergent and Nucleophile‐Assisted Rearrangement in the Construction of Pyrrolo[2,1‐b][3]benzazepine and Pyrido[2,1‐a]isoquinoline Scaffolds
T2 - Chemistry - A European Journal
AU - Obydennik, Arina Y.
AU - Titov, Alexander A
AU - Sbei, Najoua
AU - Borisova, T.
AU - Sokolova, Irina L.
AU - Rybakov, Victor B.
AU - Sharma, Nandini
AU - Voskressensky, Leonid G.
AU - Varlamov, Alexey V.
PY - 2023
DA - 2023/11/20
PB - Wiley
IS - 3
VL - 30
PMID - 37864779
SN - 0947-6539
SN - 1521-3765
ER -
BibTex
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@article{2023_Obydennik,
author = {Arina Y. Obydennik and Alexander A Titov and Najoua Sbei and T. Borisova and Irina L. Sokolova and Victor B. Rybakov and Nandini Sharma and Leonid G. Voskressensky and Alexey V. Varlamov},
title = {Divergent and Nucleophile‐Assisted Rearrangement in the Construction of Pyrrolo[2,1‐b][3]benzazepine and Pyrido[2,1‐a]isoquinoline Scaffolds},
journal = {Chemistry - A European Journal},
year = {2023},
volume = {30},
publisher = {Wiley},
month = {nov},
url = {https://doi.org/10.1002/chem.202302919},
number = {3},
doi = {10.1002/chem.202302919}
}