Asymmetric Catalytic Aziridination to Synthesize Spiro‐aziridine Oxindoles
Publication type: Journal Article
Publication date: 2025-03-04
scimago Q1
wos Q2
SJR: 0.981
CiteScore: 6.7
Impact factor: 3.7
ISSN: 09476539, 15213765
Abstract
Asymmetric catalytic aza‐Michael‐initiated ring closure of methyleneindolinones with N‐tosyloxycarbamates has been established. The reaction using a chiral nickel complex catalyst enabled the formation of a series of spiro‐aziridine oxindoles in good yields (up to 99 %) with high stereoselectivity (up to 97 % ee, >19 : 1 dr) under mild reaction conditions. Ring‐opening of spiro‐aziridine oxindole leads to formation of glycinate‐bearing oxindoles with retention of configuration.
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6
Total citations:
6
Citations from 2024:
5
(83.33%)
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Qu Y. et al. Asymmetric Catalytic Aziridination to Synthesize Spiro‐aziridine Oxindoles // Chemistry - A European Journal. 2025. Vol. 31. No. 20. e202500302
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Qu Y., Liu Z., Zhou Y., Feng X., Liu X. Asymmetric Catalytic Aziridination to Synthesize Spiro‐aziridine Oxindoles // Chemistry - A European Journal. 2025. Vol. 31. No. 20. e202500302
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TY - JOUR
DO - 10.1002/chem.202500302
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202500302
TI - Asymmetric Catalytic Aziridination to Synthesize Spiro‐aziridine Oxindoles
T2 - Chemistry - A European Journal
AU - Qu, Yinhe
AU - Liu, Zhenzhong
AU - Zhou, Yuqiao
AU - Feng, Xiaoming
AU - Liu, Xiaohua
PY - 2025
DA - 2025/03/04
PB - Wiley
IS - 20
VL - 31
SN - 0947-6539
SN - 1521-3765
ER -
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@article{2025_Qu,
author = {Yinhe Qu and Zhenzhong Liu and Yuqiao Zhou and Xiaoming Feng and Xiaohua Liu},
title = {Asymmetric Catalytic Aziridination to Synthesize Spiro‐aziridine Oxindoles},
journal = {Chemistry - A European Journal},
year = {2025},
volume = {31},
publisher = {Wiley},
month = {mar},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202500302},
number = {20},
pages = {e202500302},
doi = {10.1002/chem.202500302}
}
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