Asymmetric aldol reactions catalyzed by efficient and recyclable silica-supported proline-based peptides
Тип публикации: Journal Article
Дата публикации: 2009-04-01
scimago Q2
wos Q1
БС2
SJR: 0.682
CiteScore: 4.9
Impact factor: 3
ISSN: 08990042, 1520636X
PubMed ID:
18570310
Catalysis
Organic Chemistry
Drug Discovery
Spectroscopy
Pharmacology
Analytical Chemistry
Краткое описание
A series of silica-supported proline-based peptides were synthesized and applied as catalysts for direct asymmetric intermolecular aldol reactions. Among these, a peptide with two L-proline units was found to be the most efficient one for the asymmetric aldol reactions between acetone and aromatic aldehydes. The reactions generated the corresponding products with satisfactory isolated yields (up to 97%) and enantiomeric excesses (up to 96%) in the presence of this catalyst (5 mol %). Furthermore, the silica-supported organocatalyst could be recovered and recycled by a simple filtration of the reaction solution and used for five consecutive trials without loss of its reactivity.
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ГОСТ
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Yan J., Wang L. Asymmetric aldol reactions catalyzed by efficient and recyclable silica-supported proline-based peptides // Chirality. 2009. Vol. 21. No. 4. pp. 413-420.
ГОСТ со всеми авторами (до 50)
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Yan J., Wang L. Asymmetric aldol reactions catalyzed by efficient and recyclable silica-supported proline-based peptides // Chirality. 2009. Vol. 21. No. 4. pp. 413-420.
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TY - JOUR
DO - 10.1002/chir.20603
UR - https://doi.org/10.1002/chir.20603
TI - Asymmetric aldol reactions catalyzed by efficient and recyclable silica-supported proline-based peptides
T2 - Chirality
AU - Yan, Jincan
AU - Wang, Lei
PY - 2009
DA - 2009/04/01
PB - Wiley
SP - 413-420
IS - 4
VL - 21
PMID - 18570310
SN - 0899-0042
SN - 1520-636X
ER -
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@article{2009_Yan,
author = {Jincan Yan and Lei Wang},
title = {Asymmetric aldol reactions catalyzed by efficient and recyclable silica-supported proline-based peptides},
journal = {Chirality},
year = {2009},
volume = {21},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/chir.20603},
number = {4},
pages = {413--420},
doi = {10.1002/chir.20603}
}
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MLA
Скопировать
Yan, Jincan, and Lei Wang. “Asymmetric aldol reactions catalyzed by efficient and recyclable silica-supported proline-based peptides.” Chirality, vol. 21, no. 4, Apr. 2009, pp. 413-420. https://doi.org/10.1002/chir.20603.