Controlled One‐pot Synthesis of PdAg Nanoparticles and Their Application in the Semi‐hydrogenation of Acetylene in Ethylene‐rich Mixtures
Jorge A Delgado
1
,
Olivia Benkirane
1
,
Suzanne Lachaux
1
,
Carmen Claver
1, 2
,
Joan Ferré
3
,
Daniel Curulla Ferré
4
,
Cyril Godard
2
1
EURECAT Centre Tecnològic de Catalunya Carrer Marcel lí Domingo, 2–6 43007 Tarragona Spain
|
4
Total Research and Technology Feluy B-7181 Seneffe (Belgium)
|
Publication type: Journal Article
Publication date: 2022-04-06
Materials Chemistry
Biomaterials
Energy Engineering and Power Technology
Renewable Energy, Sustainability and the Environment
Abstract
Here we report the synthesis of highly functionalized nanomaterials carefully nanoengineered to catalyze the semi-hydrogenation of acetylene in ethylene rich mixtures. Surface functionalization and structure modification of a series of bimetallic PdAg nanoparticles was performed using HHDMA as stabilizer and alloying the active palladium phase with silver. The reactivity of these materials demonstrated the applicability of HHDMA stabilized NPs in a gas phase reaction of industrial interest and the success of combining several strategies for the enhancement of the alkene selectivity.
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11
Total citations:
11
Citations from 2024:
7
(63.63%)
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GOST
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Delgado J. A. et al. Controlled One‐pot Synthesis of PdAg Nanoparticles and Their Application in the Semi‐hydrogenation of Acetylene in Ethylene‐rich Mixtures // ChemNanoMat. 2022. Vol. 8. No. 5.
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Delgado J. A., Benkirane O., Lachaux S., Claver C., Ferré J., Curulla Ferré D., Godard C. Controlled One‐pot Synthesis of PdAg Nanoparticles and Their Application in the Semi‐hydrogenation of Acetylene in Ethylene‐rich Mixtures // ChemNanoMat. 2022. Vol. 8. No. 5.
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TY - JOUR
DO - 10.1002/cnma.202200058
UR - https://doi.org/10.1002/cnma.202200058
TI - Controlled One‐pot Synthesis of PdAg Nanoparticles and Their Application in the Semi‐hydrogenation of Acetylene in Ethylene‐rich Mixtures
T2 - ChemNanoMat
AU - Delgado, Jorge A
AU - Benkirane, Olivia
AU - Lachaux, Suzanne
AU - Claver, Carmen
AU - Ferré, Joan
AU - Curulla Ferré, Daniel
AU - Godard, Cyril
PY - 2022
DA - 2022/04/06
PB - Wiley
IS - 5
VL - 8
SN - 2199-692X
ER -
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@article{2022_Delgado,
author = {Jorge A Delgado and Olivia Benkirane and Suzanne Lachaux and Carmen Claver and Joan Ferré and Daniel Curulla Ferré and Cyril Godard},
title = {Controlled One‐pot Synthesis of PdAg Nanoparticles and Their Application in the Semi‐hydrogenation of Acetylene in Ethylene‐rich Mixtures},
journal = {ChemNanoMat},
year = {2022},
volume = {8},
publisher = {Wiley},
month = {apr},
url = {https://doi.org/10.1002/cnma.202200058},
number = {5},
doi = {10.1002/cnma.202200058}
}