ChemPhysChem

, volume 16 , issue 15 , pages 3318-3324

Highly Oxidized Platinum Nanoparticles Prepared through Radio-Frequency Sputtering: Thermal Stability and Reaction Probability towards CO

Dmitry A Svintsitskiy ^{1, 2}

Lidiya Kibis ^{1, 2}

Andrey Stadnichenko ^{1, 2}

Sergei V Koscheev ^{1, 2}

Vladimir I Zaikovskii ^{1, 2}

Andrei Boronin ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

Boreskov Institute of Catalysis; Pr. Lavrentieva 5 Novosibirsk 630090 Russia |

Novosibirsk State University; Pirogova st. 2 Novosibirsk 630090 Russia |

Publication type: Journal Article

Publication date: 2015-08-25

Wiley

ChemPhysChem

scimago Q2

wos Q3

SJR: 0.553

CiteScore: 3.6

Impact factor: 2.2

ISSN: 14394235, 14397641

DOI: 10.1002/cphc.201500546

Copy DOI

PubMed ID: 26489061

Physical and Theoretical Chemistry

Atomic and Molecular Physics, and Optics

Abstract

Platinum‐oxide nanoparticles were prepared through the radio‐frequency (RF) discharge sputtering of a Pt electrode in an oxygen atmosphere. The structure, particles size, electronic properties, and surface composition of the RF‐sputtered particles were studied by using transmission electron microscopy and X‐ray photoelectron spectroscopy. The application of the RF discharge method resulted in the formation of highly oxidized Pt⁴⁺ species that were stable under ultrahigh vacuum conditions up to 100 °C, indicating the capability of Pt⁴⁺–O species to play an important role in the oxidation catalysis under real conditions. The thermal stability and reaction probability of Pt⁴⁺ oxide species were analyzed and compared with those of Pt²⁺ species. The reaction probability of PtO₂ nanoparticles at 90 °C was found to be about ten times higher than that of PtO‐like structures.

Found

16 citations

Svintsitskiy Dmitry

PhD in Chemistry

74 publications, 1 855 citations, 36 reviews

h-index: 25

Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences

6 citations

Gerasimov Evgeny

🥼

PhD in Physics and Mathematics

389 publications, 5 276 citations, 29 reviews

h-index: 36

Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences

Novosibirsk State University

1 citation

Prosvirin Igor

PhD in Chemistry

359 publications, 7 859 citations, 2 reviews

h-index: 47

Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences

1 citation

Kostyukov Anton

PhD in Physics and Mathematics

47 publications, 507 citations, 27 reviews

h-index: 14

Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences

Novosibirsk State University

Research interests

Laser ablation

Luminescent materials

Materials Chemistry

Optical materials

1 citation

Zaguzin Alexander

🥼 🤝

PhD in Chemistry

25 publications, 132 citations, 1 review

h-index: 8

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Research interests

Coordination Chemistry

Halogen connection

Metal-organic coordination polymers

Supramolecular chemistry

1 citation

Vodyankina Olga

DSc in Chemistry, professor

142 publications, 2 134 citations, 61 reviews

h-index: 24

Tomsk State University

Research interests

Heterogeneous catalysis

Metal-organic coordination polymers

Photocatalysis

Photocatalysts

Reaction mechanisms

Selective liquid phase oxidation

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GOST Copy

Svintsitskiy D. A. et al. Highly Oxidized Platinum Nanoparticles Prepared through Radio-Frequency Sputtering: Thermal Stability and Reaction Probability towards CO // ChemPhysChem. 2015. Vol. 16. No. 15. pp. 3318-3324.

GOST all authors (up to 50) Copy

Svintsitskiy D. A., Kibis L., Stadnichenko A., Koscheev S. V., Zaikovskii V. I., Boronin A. Highly Oxidized Platinum Nanoparticles Prepared through Radio-Frequency Sputtering: Thermal Stability and Reaction Probability towards CO // ChemPhysChem. 2015. Vol. 16. No. 15. pp. 3318-3324.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/cphc.201500546

UR - https://doi.org/10.1002/cphc.201500546

TI - Highly Oxidized Platinum Nanoparticles Prepared through Radio-Frequency Sputtering: Thermal Stability and Reaction Probability towards CO

T2 - ChemPhysChem

AU - Svintsitskiy, Dmitry A

AU - Kibis, Lidiya

AU - Stadnichenko, Andrey

AU - Koscheev, Sergei V

AU - Zaikovskii, Vladimir I

AU - Boronin, Andrei

PY - 2015

DA - 2015/08/25

PB - Wiley

SP - 3318-3324

IS - 15

VL - 16

PMID - 26489061

SN - 1439-4235

SN - 1439-7641

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2015_Svintsitskiy,

author = {Dmitry A Svintsitskiy and Lidiya Kibis and Andrey Stadnichenko and Sergei V Koscheev and Vladimir I Zaikovskii and Andrei Boronin},

title = {Highly Oxidized Platinum Nanoparticles Prepared through Radio-Frequency Sputtering: Thermal Stability and Reaction Probability towards CO},

journal = {ChemPhysChem},

year = {2015},

volume = {16},

publisher = {Wiley},

month = {aug},

url = {https://doi.org/10.1002/cphc.201500546},

number = {15},

pages = {3318--3324},

doi = {10.1002/cphc.201500546}

}

MLA

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MLA Copy

Svintsitskiy, Dmitry A., et al. “Highly Oxidized Platinum Nanoparticles Prepared through Radio-Frequency Sputtering: Thermal Stability and Reaction Probability towards CO.” ChemPhysChem, vol. 16, no. 15, Aug. 2015, pp. 3318-3324. https://doi.org/10.1002/cphc.201500546.

Publisher

Wiley

Journal

ChemPhysChem

scimago Q2

wos Q3

SJR

0.553

CiteScore

3.6

Impact factor

2.2

ISSN

14394235 (Print)

14397641 (Electronic)

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