Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields
Kai Buckenmaier
1
,
Klaus Scheffler
1, 2
,
Markus Plaumann
3
,
Paul Fehling
1
,
Johannes Bernarding
3
,
Matthias Rudolph
1, 4
,
Christoph Back
4
,
Dieter Koelle
4
,
R. Kleiner
4
,
Jan‐Bernd Hövener
5
,
Andrey Pravdivtsev
5
Publication type: Journal Article
Publication date: 2019-10-17
scimago Q2
wos Q3
SJR: 0.553
CiteScore: 3.6
Impact factor: 2.2
ISSN: 14394235, 14397641
PubMed ID:
31536665
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
Abstract
The development of hyperpolarization technologies enabled several yet exotic NMR applications at low and ultra-low fields (ULF), where without hyperpolarization even the detection of a signal from analytes is a challenge. Herein, we present a method for the simultaneous excitation and observation of homo- and heteronuclear multiple quantum coherences (from zero up to the third-order), which give an additional degree of freedom for ULF NMR experiments, where the chemical shift variation is negligible. The approach is based on heteronuclear correlated spectroscopy (COSY); its combination with a phase-cycling scheme allows the selective observation of multiple quantum coherences of different orders. The nonequilibrium spin state and multiple spin orders are generated by signal amplification by reversible exchange (SABRE) and detected at ULF with a superconducting quantum interference device (SQUID)-based NMR system.
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Metrics
20
Total citations:
20
Citations from 2025:
5
(25%)
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GOST
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Buckenmaier K. et al. Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields // ChemPhysChem. 2019. Vol. 20. No. 21. pp. 2823-2829.
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Buckenmaier K., Scheffler K., Plaumann M., Fehling P., Bernarding J., Rudolph M., Back C., Koelle D., Kleiner R., Hövener J., Pravdivtsev A. Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields // ChemPhysChem. 2019. Vol. 20. No. 21. pp. 2823-2829.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/cphc.201900757
UR - https://doi.org/10.1002/cphc.201900757
TI - Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields
T2 - ChemPhysChem
AU - Buckenmaier, Kai
AU - Scheffler, Klaus
AU - Plaumann, Markus
AU - Fehling, Paul
AU - Bernarding, Johannes
AU - Rudolph, Matthias
AU - Back, Christoph
AU - Koelle, Dieter
AU - Kleiner, R.
AU - Hövener, Jan‐Bernd
AU - Pravdivtsev, Andrey
PY - 2019
DA - 2019/10/17
PB - Wiley
SP - 2823-2829
IS - 21
VL - 20
PMID - 31536665
SN - 1439-4235
SN - 1439-7641
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Buckenmaier,
author = {Kai Buckenmaier and Klaus Scheffler and Markus Plaumann and Paul Fehling and Johannes Bernarding and Matthias Rudolph and Christoph Back and Dieter Koelle and R. Kleiner and Jan‐Bernd Hövener and Andrey Pravdivtsev},
title = {Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields},
journal = {ChemPhysChem},
year = {2019},
volume = {20},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/cphc.201900757},
number = {21},
pages = {2823--2829},
doi = {10.1002/cphc.201900757}
}
Cite this
MLA
Copy
Buckenmaier, Kai, et al. “Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields.” ChemPhysChem, vol. 20, no. 21, Oct. 2019, pp. 2823-2829. https://doi.org/10.1002/cphc.201900757.