volume 20 issue 21 pages 2823-2829

Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields

Kai Buckenmaier 1
Klaus Scheffler 1, 2
Paul Fehling 1
Johannes Bernarding 3
Matthias Rudolph 1, 4
Christoph Back 4
Dieter Koelle 4
R. Kleiner 4
Jan‐Bernd Hövener 5
Andrey Pravdivtsev 5
Publication typeJournal Article
Publication date2019-10-17
scimago Q2
wos Q3
SJR0.553
CiteScore3.6
Impact factor2.2
ISSN14394235, 14397641
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
Abstract
The development of hyperpolarization technologies enabled several yet exotic NMR applications at low and ultra-low fields (ULF), where without hyperpolarization even the detection of a signal from analytes is a challenge. Herein, we present a method for the simultaneous excitation and observation of homo- and heteronuclear multiple quantum coherences (from zero up to the third-order), which give an additional degree of freedom for ULF NMR experiments, where the chemical shift variation is negligible. The approach is based on heteronuclear correlated spectroscopy (COSY); its combination with a phase-cycling scheme allows the selective observation of multiple quantum coherences of different orders. The nonequilibrium spin state and multiple spin orders are generated by signal amplification by reversible exchange (SABRE) and detected at ULF with a superconducting quantum interference device (SQUID)-based NMR system.
Found 
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GOST Copy
Buckenmaier K. et al. Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields // ChemPhysChem. 2019. Vol. 20. No. 21. pp. 2823-2829.
GOST all authors (up to 50) Copy
Buckenmaier K., Scheffler K., Plaumann M., Fehling P., Bernarding J., Rudolph M., Back C., Koelle D., Kleiner R., Hövener J., Pravdivtsev A. Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields // ChemPhysChem. 2019. Vol. 20. No. 21. pp. 2823-2829.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/cphc.201900757
UR - https://doi.org/10.1002/cphc.201900757
TI - Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields
T2 - ChemPhysChem
AU - Buckenmaier, Kai
AU - Scheffler, Klaus
AU - Plaumann, Markus
AU - Fehling, Paul
AU - Bernarding, Johannes
AU - Rudolph, Matthias
AU - Back, Christoph
AU - Koelle, Dieter
AU - Kleiner, R.
AU - Hövener, Jan‐Bernd
AU - Pravdivtsev, Andrey
PY - 2019
DA - 2019/10/17
PB - Wiley
SP - 2823-2829
IS - 21
VL - 20
PMID - 31536665
SN - 1439-4235
SN - 1439-7641
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Buckenmaier,
author = {Kai Buckenmaier and Klaus Scheffler and Markus Plaumann and Paul Fehling and Johannes Bernarding and Matthias Rudolph and Christoph Back and Dieter Koelle and R. Kleiner and Jan‐Bernd Hövener and Andrey Pravdivtsev},
title = {Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields},
journal = {ChemPhysChem},
year = {2019},
volume = {20},
publisher = {Wiley},
month = {oct},
url = {https://doi.org/10.1002/cphc.201900757},
number = {21},
pages = {2823--2829},
doi = {10.1002/cphc.201900757}
}
MLA
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MLA Copy
Buckenmaier, Kai, et al. “Multiple Quantum Coherences Hyperpolarized at Ultra‐Low Fields.” ChemPhysChem, vol. 20, no. 21, Oct. 2019, pp. 2823-2829. https://doi.org/10.1002/cphc.201900757.