Synergistic and Diminutive Effects between Regium and Aerogen Bonds
Publication type: Journal Article
Publication date: 2020-10-01
scimago Q2
wos Q3
SJR: 0.553
CiteScore: 3.6
Impact factor: 2.2
ISSN: 14394235, 14397641
PubMed ID:
32889745
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
Abstract
The aerogen bond is formed in complexes of HCN−XeF2O and C2H4−XeF2O. The lone pair on the N atom of HCN is a better electron donor in the aerogen bond than the π electron on the C=C bond of C2H4. The coinage substitution strengthens the aerogen bond in MCN−XeF2O (M=Cu, Ag, and Au) and its enhancing effect becomes larger in the Au<Cu<Ag pattern. The aerogen bond is further enhanced by the regium bond in C2H2−MCN−XeF2O and C2H4−MCN−XeF2O, but is weakened by the regium bond in MCN−C2H4−XeF2O and C2(CN)4−MCN−XeF2O. Simultaneously, the regium bond is also strengthened or weakened in these triads. The synergistic and diminutive effects between regium and aerogen bonds have been explained by means of charge transfer and electrostatic potentials.
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Total citations:
27
Citations from 2024:
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(44.44%)
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GOST
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Wang R. et al. Synergistic and Diminutive Effects between Regium and Aerogen Bonds // ChemPhysChem. 2020. Vol. 21. No. 21. pp. 2426-2431.
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Wang R., Wang Z., Yu X., Li Q. Synergistic and Diminutive Effects between Regium and Aerogen Bonds // ChemPhysChem. 2020. Vol. 21. No. 21. pp. 2426-2431.
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RIS
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TY - JOUR
DO - 10.1002/cphc.202000720
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cphc.202000720
TI - Synergistic and Diminutive Effects between Regium and Aerogen Bonds
T2 - ChemPhysChem
AU - Wang, Ruijing
AU - Wang, Zheng
AU - Yu, Xuefang
AU - Li, Qingzhong
PY - 2020
DA - 2020/10/01
PB - Wiley
SP - 2426-2431
IS - 21
VL - 21
PMID - 32889745
SN - 1439-4235
SN - 1439-7641
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Wang,
author = {Ruijing Wang and Zheng Wang and Xuefang Yu and Qingzhong Li},
title = {Synergistic and Diminutive Effects between Regium and Aerogen Bonds},
journal = {ChemPhysChem},
year = {2020},
volume = {21},
publisher = {Wiley},
month = {oct},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cphc.202000720},
number = {21},
pages = {2426--2431},
doi = {10.1002/cphc.202000720}
}
Cite this
MLA
Copy
Wang, Ruijing, et al. “Synergistic and Diminutive Effects between Regium and Aerogen Bonds.” ChemPhysChem, vol. 21, no. 21, Oct. 2020, pp. 2426-2431. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cphc.202000720.
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