ChemSusChem, volume 8, issue 6, pages 1034-1042
New Iron Pyridylamino-Bis(Phenolate) Catalyst for Converting CO2into Cyclic Carbonates and Cross-Linked Polycarbonates
Masoumeh Taherimehr
1
,
João Paulo Cardoso Costa Sertã
1
,
Arjan W Kleij
2
,
Christopher J Whiteoak
2
,
Paolo P. Pescarmona
3, 4
2
Publication type: Journal Article
Publication date: 2015-02-17
General Chemical Engineering
General Materials Science
General Energy
Environmental Chemistry
Abstract
CO2 meets epoxides: Iron pyridylamino-bis(phenolate) complexes are highly active catalysts for the atom-efficient reaction of CO2 with a variety of epoxides. The selectivity can be switched between the cyclic or polymeric carbonate when using cyclic epoxides such as cyclohexene oxide and 1,2-epoxy-4-vinylcyclohexaneas substrates. Cross-linking of the obtained poly(vinylcyclohexene carbonate) leads to substantial increase in the Tg and chemical resistance of the polymer.
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Taherimehr M. et al. New Iron Pyridylamino-Bis(Phenolate) Catalyst for Converting CO2into Cyclic Carbonates and Cross-Linked Polycarbonates // ChemSusChem. 2015. Vol. 8. No. 6. pp. 1034-1042.
GOST all authors (up to 50)
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Taherimehr M., Sertã J. P. C. C., Kleij A. W., Whiteoak C. J., Pescarmona P. P. New Iron Pyridylamino-Bis(Phenolate) Catalyst for Converting CO2into Cyclic Carbonates and Cross-Linked Polycarbonates // ChemSusChem. 2015. Vol. 8. No. 6. pp. 1034-1042.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/cssc.201403323
UR - https://doi.org/10.1002/cssc.201403323
TI - New Iron Pyridylamino-Bis(Phenolate) Catalyst for Converting CO2into Cyclic Carbonates and Cross-Linked Polycarbonates
T2 - ChemSusChem
AU - Taherimehr, Masoumeh
AU - Sertã, João Paulo Cardoso Costa
AU - Kleij, Arjan W
AU - Whiteoak, Christopher J
AU - Pescarmona, Paolo P.
PY - 2015
DA - 2015/02/17
PB - Wiley
SP - 1034-1042
IS - 6
VL - 8
SN - 1864-5631
SN - 1864-564X
ER -
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BibTex (up to 50 authors)
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@article{2015_Taherimehr,
author = {Masoumeh Taherimehr and João Paulo Cardoso Costa Sertã and Arjan W Kleij and Christopher J Whiteoak and Paolo P. Pescarmona},
title = {New Iron Pyridylamino-Bis(Phenolate) Catalyst for Converting CO2into Cyclic Carbonates and Cross-Linked Polycarbonates},
journal = {ChemSusChem},
year = {2015},
volume = {8},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002/cssc.201403323},
number = {6},
pages = {1034--1042},
doi = {10.1002/cssc.201403323}
}
Cite this
MLA
Copy
Taherimehr, Masoumeh, et al. “New Iron Pyridylamino-Bis(Phenolate) Catalyst for Converting CO2into Cyclic Carbonates and Cross-Linked Polycarbonates.” ChemSusChem, vol. 8, no. 6, Feb. 2015, pp. 1034-1042. https://doi.org/10.1002/cssc.201403323.