Current Advances in the Sustainable Conversion of 5‐Hydroxymethylfurfural into 2,5‐Furandicarboxylic Acid
Publication type: Journal Article
Publication date: 2022-05-13
scimago Q1
wos Q1
SJR: 1.845
CiteScore: 13.1
Impact factor: 6.6
ISSN: 18645631, 1864564X
PubMed ID:
35438242
General Chemical Engineering
General Materials Science
General Energy
Environmental Chemistry
Abstract
2,5-Furandicarboxylic acid (FDCA) is currently considered one of the most relevant bio-sourced building blocks, representing a fully sustainable competitor for terephthalic acid as well as the main component in green polymers such as poly(ethylene 2,5-furandicarboxylate) (PEF). The oxidation of biobased 5-hydroxymethylfurfural (HMF) represents the most straightforward approach to obtain FDCA, thus attracting the attention of both academia and industries, as testified by Avantium with the creation of a new plant expected to produce 5000 tons per year. Several approaches allow the oxidation of HMF to FDCA. Metal-mediated homogeneous and heterogeneous catalysis, metal-free catalysis, electrochemical approaches, light-mediated procedures, as well as biocatalytic processes share the target to achieve FDCA in high yield and mild conditions. This Review aims to give an up-to-date overview of the current developments in the main synthetic pathways to obtain FDCA from HMF, with a specific focus on process sustainability.
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Metrics
104
Total citations:
104
Citations from 2025:
50
(48.08%)
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Totaro G. et al. Current Advances in the Sustainable Conversion of 5‐Hydroxymethylfurfural into 2,5‐Furandicarboxylic Acid // ChemSusChem. 2022. Vol. 15. No. 13.
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Totaro G., Sisti L., Marchese P., Colonna M., Romano A., Gioia C., Vannini M., Celli A. Current Advances in the Sustainable Conversion of 5‐Hydroxymethylfurfural into 2,5‐Furandicarboxylic Acid // ChemSusChem. 2022. Vol. 15. No. 13.
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RIS
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TY - JOUR
DO - 10.1002/cssc.202200501
UR - https://doi.org/10.1002/cssc.202200501
TI - Current Advances in the Sustainable Conversion of 5‐Hydroxymethylfurfural into 2,5‐Furandicarboxylic Acid
T2 - ChemSusChem
AU - Totaro, Grazia
AU - Sisti, Laura
AU - Marchese, Paola
AU - Colonna, Martino
AU - Romano, Angela
AU - Gioia, Claudio
AU - Vannini, Micaela
AU - Celli, Annamaria
PY - 2022
DA - 2022/05/13
PB - Wiley
IS - 13
VL - 15
PMID - 35438242
SN - 1864-5631
SN - 1864-564X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2022_Totaro,
author = {Grazia Totaro and Laura Sisti and Paola Marchese and Martino Colonna and Angela Romano and Claudio Gioia and Micaela Vannini and Annamaria Celli},
title = {Current Advances in the Sustainable Conversion of 5‐Hydroxymethylfurfural into 2,5‐Furandicarboxylic Acid},
journal = {ChemSusChem},
year = {2022},
volume = {15},
publisher = {Wiley},
month = {may},
url = {https://doi.org/10.1002/cssc.202200501},
number = {13},
doi = {10.1002/cssc.202200501}
}