Wiley
European Journal of Inorganic Chemistry
,  volume 2004 ,  issue 4 ,  pages 771-775

Direct hydride/silyl exchange - Synthesis and X-ray study of the bis(silyl) complex [Cp2NbH(SiCl3)2]

Publication type: Journal Article
Publication date: 2004-02-18
Wiley
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract

Niobocene trihydride reacts directly with the chlorosilanes SiCl2R′R′′ (R′, R′′ = Me, Ph) and SiCl3Me to give the dihydridomonosilyl derivatives [Cp2Nb(H)2(SiClnR3−n)] (n = 1, 2), whereas the analogous reaction with SiCl4 affords [Cp2Nb(H)2(SiCl3)] and the bis(silyl) complex [Cp2NbH(SiCl3)2], whose X‐ray structure was determined. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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Dorogov K. Yu. et al. Direct hydride/silyl exchange - Synthesis and X-ray study of the bis(silyl) complex [Cp2NbH(SiCl3)2] // European Journal of Inorganic Chemistry. 2004. Vol. 2004. No. 4. pp. 771-775.
GOST all authors (up to 50) Copy
Dorogov K. Yu., Churakov A. V., Kuz'mina L. G., Howard J. A., Nikonov G. I. Direct hydride/silyl exchange - Synthesis and X-ray study of the bis(silyl) complex [Cp2NbH(SiCl3)2] // European Journal of Inorganic Chemistry. 2004. Vol. 2004. No. 4. pp. 771-775.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/ejic.200300134
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200300134
TI - Direct hydride/silyl exchange - Synthesis and X-ray study of the bis(silyl) complex [Cp2NbH(SiCl3)2]
T2 - European Journal of Inorganic Chemistry
AU - Dorogov, Konstantin Yu
AU - Churakov, Andrei V.
AU - Kuz'mina, Lyudmila G.
AU - Howard, Judith A.
AU - Nikonov, G. I.
PY - 2004
DA - 2004/02/18
PB - Wiley
SP - 771-775
IS - 4
VL - 2004
SN - 1434-1948
SN - 1099-0682
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2004_Dorogov,
author = {Konstantin Yu Dorogov and Andrei V. Churakov and Lyudmila G. Kuz'mina and Judith A. Howard and G. I. Nikonov},
title = {Direct hydride/silyl exchange - Synthesis and X-ray study of the bis(silyl) complex [Cp2NbH(SiCl3)2]},
journal = {European Journal of Inorganic Chemistry},
year = {2004},
volume = {2004},
publisher = {Wiley},
month = {feb},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200300134},
number = {4},
pages = {771--775},
doi = {10.1002/ejic.200300134}
}
MLA
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MLA Copy
Dorogov, Konstantin Yu., et al. “Direct hydride/silyl exchange - Synthesis and X-ray study of the bis(silyl) complex [Cp2NbH(SiCl3)2].” European Journal of Inorganic Chemistry, vol. 2004, no. 4, Feb. 2004, pp. 771-775. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200300134.