volume 2004 issue 10 pages 2123-2129

Reaction of [In(NEt2)3]2 with N(CH 2CH2NSiMe3H)3: Synthesis and characterization of new azaindatranes and azaindocane

Publication typeJournal Article
Publication date2004-05-01
scimago Q2
wos Q3
SJR0.459
CiteScore3.9
Impact factor2.0
ISSN14341948, 10990682
Inorganic Chemistry
Abstract

[In(NEt2)3]2 and N(CH2CH2NSiMe3H)3 react to yield monomeric azaindatrane 1, N(CH2CH2NSiMe3)3In, which is unstable without additional donor (e.g. pyridine), turning into dimeric azaindatrane 2, [N(CH2CH2NSiMe3)2(CH2CH2NH)In]2. An intermediate product of this transformation is oligomeric azaindocane 3, [N(CH2CH2NSiMe3)2In(CH2CH2NSiMe3)]3. The composition and structures of new compounds have been established by 1H and 13C NMR spectroscopy. The crystal structures of Py, trans2, and 3 have been determined by X‐ray diffraction studies. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)

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Shutov P. L. et al. Reaction of [In(NEt2)3]2 with N(CH 2CH2NSiMe3H)3: Synthesis and characterization of new azaindatranes and azaindocane // European Journal of Inorganic Chemistry. 2004. Vol. 2004. No. 10. pp. 2123-2129.
GOST all authors (up to 50) Copy
Shutov P. L., Karlov S. S., Harms K., Churakov A. V., Lorberth J., Zaitseva G. S. Reaction of [In(NEt2)3]2 with N(CH 2CH2NSiMe3H)3: Synthesis and characterization of new azaindatranes and azaindocane // European Journal of Inorganic Chemistry. 2004. Vol. 2004. No. 10. pp. 2123-2129.
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TY - JOUR
DO - 10.1002/ejic.200300875
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200300875
TI - Reaction of [In(NEt2)3]2 with N(CH 2CH2NSiMe3H)3: Synthesis and characterization of new azaindatranes and azaindocane
T2 - European Journal of Inorganic Chemistry
AU - Shutov, Pavel L
AU - Karlov, Sergey S.
AU - Harms, K.
AU - Churakov, Andrei V.
AU - Lorberth, Jörg
AU - Zaitseva, Galina S.
PY - 2004
DA - 2004/05/01
PB - Wiley
SP - 2123-2129
IS - 10
VL - 2004
SN - 1434-1948
SN - 1099-0682
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2004_Shutov,
author = {Pavel L Shutov and Sergey S. Karlov and K. Harms and Andrei V. Churakov and Jörg Lorberth and Galina S. Zaitseva},
title = {Reaction of [In(NEt2)3]2 with N(CH 2CH2NSiMe3H)3: Synthesis and characterization of new azaindatranes and azaindocane},
journal = {European Journal of Inorganic Chemistry},
year = {2004},
volume = {2004},
publisher = {Wiley},
month = {may},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200300875},
number = {10},
pages = {2123--2129},
doi = {10.1002/ejic.200300875}
}
MLA
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MLA Copy
Shutov, Pavel L., et al. “Reaction of [In(NEt2)3]2 with N(CH 2CH2NSiMe3H)3: Synthesis and characterization of new azaindatranes and azaindocane.” European Journal of Inorganic Chemistry, vol. 2004, no. 10, May. 2004, pp. 2123-2129. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.200300875.