volume 2003 issue 1 pages 149-163

Synthesis, Crystal Structure, and Photophysical and Magnetic Properties of Dimeric and Polymeric Lanthanide Complexes with Benzoic Acid and Its Derivatives

Publication typeJournal Article
Publication date2002-12-16
scimago Q2
wos Q3
SJR0.459
CiteScore3.9
Impact factor2.0
ISSN14341948, 10990682
Inorganic Chemistry
Abstract
A new family of lanthanide carboxylate complexes with benzoic acid and its derivatives was synthesised and characterised. The structures of the complexes were established by X-ray crystallography, which revealed that various chelating modes of the carboxylate ligands are present on the metal ion, resulting in the formation of dimeric and polymeric skeletons. The photophysical properties of the Eu and Tb complexes were studied: the complexes exhibited sensitised luminescence in the visible spectral region, but the luminescence intensities and lifetimes were very sensitive to quenching by the OH groups of methanol molecules. The solid-state magnetic properties of the Gd and Tb complexes demonstrated the presence of weak antiferromagnetic exchange interactions at very low temperatures, caused by interaction between the neighbouring ions along the chain. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2003)
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GOST Copy
Lam A. W. H. et al. Synthesis, Crystal Structure, and Photophysical and Magnetic Properties of Dimeric and Polymeric Lanthanide Complexes with Benzoic Acid and Its Derivatives // European Journal of Inorganic Chemistry. 2002. Vol. 2003. No. 1. pp. 149-163.
GOST all authors (up to 50) Copy
Lam A. W. H., Wong W., Gao S., Wen G., Zhang X. X. Synthesis, Crystal Structure, and Photophysical and Magnetic Properties of Dimeric and Polymeric Lanthanide Complexes with Benzoic Acid and Its Derivatives // European Journal of Inorganic Chemistry. 2002. Vol. 2003. No. 1. pp. 149-163.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1002/ejic.200390021
UR - https://doi.org/10.1002/ejic.200390021
TI - Synthesis, Crystal Structure, and Photophysical and Magnetic Properties of Dimeric and Polymeric Lanthanide Complexes with Benzoic Acid and Its Derivatives
T2 - European Journal of Inorganic Chemistry
AU - Lam, Alex Wai Hing
AU - Wong, Wing-Tak
AU - Gao, Song
AU - Wen, Gehui
AU - Zhang, Xi Xiang
PY - 2002
DA - 2002/12/16
PB - Wiley
SP - 149-163
IS - 1
VL - 2003
SN - 1434-1948
SN - 1099-0682
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2002_Lam,
author = {Alex Wai Hing Lam and Wing-Tak Wong and Song Gao and Gehui Wen and Xi Xiang Zhang},
title = {Synthesis, Crystal Structure, and Photophysical and Magnetic Properties of Dimeric and Polymeric Lanthanide Complexes with Benzoic Acid and Its Derivatives},
journal = {European Journal of Inorganic Chemistry},
year = {2002},
volume = {2003},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/ejic.200390021},
number = {1},
pages = {149--163},
doi = {10.1002/ejic.200390021}
}
MLA
Cite this
MLA Copy
Lam, Alex Wai Hing, et al. “Synthesis, Crystal Structure, and Photophysical and Magnetic Properties of Dimeric and Polymeric Lanthanide Complexes with Benzoic Acid and Its Derivatives.” European Journal of Inorganic Chemistry, vol. 2003, no. 1, Dec. 2002, pp. 149-163. https://doi.org/10.1002/ejic.200390021.