Stabilized germylenes based on diethylenetriamines and related diamines: Synthesis, structures, and chemical properties
A series of novel, low‐valent germanium compounds 2a–2j based on four diethylenetriamines 1a–1d, (methyl)bis(pyrrol‐2‐ylmethyl)amine (1e), N,N′‐(sulfanediyldibenzene‐2,1‐diyl)bis(pentafluoroaniline) (1f), N,N′‐(oxydibenzene‐2,1‐diyl)bis(pentafluoroaniline) (1g), and (pentafluorophenyl)amines 1i and 1j have been obtained either by the reaction of Ge[N(SiMe3)2]2 with various diamines (1a–1e) or by the metathesis reaction of [GeCl2·dioxane] with lithium amides. The oxidative insertion (with halogenation reagents, MeI, disulfides), [1+4] cycloaddition, and oxidation reactions of the synthesized germylenes were investigated. The compositions and structures of the novel compounds were established by elemental analysis, 1H and 13C NMR spectroscopy, and X‐ray diffraction analysis (germylenes 2b, 2i, 2j, Ge4+ compounds 5b, 7a, 7b, 8, 10, 11). All the synthesized germylenes are monomeric.
Топ-30
Журналы
|
1
2
3
4
5
|
|
|
Dalton Transactions
5 публикаций, 10.87%
|
|
|
Organometallics
4 публикации, 8.7%
|
|
|
Inorganica Chimica Acta
3 публикации, 6.52%
|
|
|
European Journal of Inorganic Chemistry
3 публикации, 6.52%
|
|
|
Acta Crystallographica Section E: Crystallographic Communications
2 публикации, 4.35%
|
|
|
Acta Crystallographica Section E Structure Reports Online
2 публикации, 4.35%
|
|
|
Journal of Organometallic Chemistry
2 публикации, 4.35%
|
|
|
Coordination Chemistry Reviews
2 публикации, 4.35%
|
|
|
Inorganic Chemistry
2 публикации, 4.35%
|
|
|
RSC Advances
2 публикации, 4.35%
|
|
|
Journal of Fluorine Chemistry
1 публикация, 2.17%
|
|
|
Zeitschrift fur Anorganische und Allgemeine Chemie
1 публикация, 2.17%
|
|
|
Monatshefte fur Chemie
1 публикация, 2.17%
|
|
|
ChemistrySelect
1 публикация, 2.17%
|
|
|
Molecules
1 публикация, 2.17%
|
|
|
Russian Chemical Bulletin
1 публикация, 2.17%
|
|
|
Mendeleev Communications
1 публикация, 2.17%
|
|
|
Chemistry - A European Journal
1 публикация, 2.17%
|
|
|
Angewandte Chemie
1 публикация, 2.17%
|
|
|
Angewandte Chemie - International Edition
1 публикация, 2.17%
|
|
|
Organic Chemistry Frontiers
1 публикация, 2.17%
|
|
|
Inorganics
1 публикация, 2.17%
|
|
|
Chemical Society Reviews
1 публикация, 2.17%
|
|
|
1
2
3
4
5
|
Издатели
|
2
4
6
8
10
12
|
|
|
Elsevier
11 публикаций, 23.91%
|
|
|
Wiley
11 публикаций, 23.91%
|
|
|
Royal Society of Chemistry (RSC)
9 публикаций, 19.57%
|
|
|
American Chemical Society (ACS)
6 публикаций, 13.04%
|
|
|
International Union of Crystallography (IUCr)
4 публикации, 8.7%
|
|
|
Springer Nature
2 публикации, 4.35%
|
|
|
MDPI
2 публикации, 4.35%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 публикация, 2.17%
|
|
|
2
4
6
8
10
12
|
- Мы не учитываем публикации, у которых нет DOI.
- Статистика публикаций обновляется еженедельно.