volume 2012 issue 23 pages 3712-3724

Stabilized germylenes based on diethylenetriamines and related diamines: Synthesis, structures, and chemical properties

Meng-Meng Huang 1, 2
Marina M. Kireenko 1
K V Zaitsev 1
Yuri F. Oprunenko 1
Judith A. Howard 4
Denis Sorokin 5
Thomas Linder 5
Jörg Sundermeyer 5
Sergey S. Karlov 1
Galina S. Zaitseva 1
Publication typeJournal Article
Publication date2012-07-04
scimago Q2
wos Q3
SJR0.459
CiteScore3.9
Impact factor2.0
ISSN14341948, 10990682
Inorganic Chemistry
Abstract

A series of novel, low‐valent germanium compounds 2a2j based on four diethylenetriamines 1a1d, (methyl)bis(pyrrol‐2‐ylmethyl)amine (1e), N,N′‐(sulfanediyldibenzene‐2,1‐diyl)bis(pentafluoroaniline) (1f), N,N′‐(oxydibenzene‐2,1‐diyl)bis(pentafluoroaniline) (1g), and (pentafluorophenyl)amines 1i and 1j have been obtained either by the reaction of Ge[N(SiMe3)2]2 with various diamines (1a1e) or by the metathesis reaction of [GeCl2·dioxane] with lithium amides. The oxidative insertion (with halogenation reagents, MeI, disulfides), [1+4] cycloaddition, and oxidation reactions of the synthesized germylenes were investigated. The compositions and structures of the novel compounds were established by elemental analysis, 1H and 13C NMR spectroscopy, and X‐ray diffraction analysis (germylenes 2b, 2i, 2j, Ge4+ compounds 5b, 7a, 7b, 8, 10, 11). All the synthesized germylenes are monomeric.

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Huang M. et al. Stabilized germylenes based on diethylenetriamines and related diamines: Synthesis, structures, and chemical properties // European Journal of Inorganic Chemistry. 2012. Vol. 2012. No. 23. pp. 3712-3724.
GOST all authors (up to 50) Copy
Huang M., Kireenko M. M., Zaitsev K. V., Oprunenko Y. F., Churakov A. V., Howard J. A., Lermontova E. K., Sorokin D., Linder T., Sundermeyer J., Karlov S. S., Zaitseva G. S. Stabilized germylenes based on diethylenetriamines and related diamines: Synthesis, structures, and chemical properties // European Journal of Inorganic Chemistry. 2012. Vol. 2012. No. 23. pp. 3712-3724.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/ejic.201200363
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201200363
TI - Stabilized germylenes based on diethylenetriamines and related diamines: Synthesis, structures, and chemical properties
T2 - European Journal of Inorganic Chemistry
AU - Huang, Meng-Meng
AU - Kireenko, Marina M.
AU - Zaitsev, K V
AU - Oprunenko, Yuri F.
AU - Churakov, Andrei V.
AU - Howard, Judith A.
AU - Lermontova, Elmira Kh.
AU - Sorokin, Denis
AU - Linder, Thomas
AU - Sundermeyer, Jörg
AU - Karlov, Sergey S.
AU - Zaitseva, Galina S.
PY - 2012
DA - 2012/07/04
PB - Wiley
SP - 3712-3724
IS - 23
VL - 2012
SN - 1434-1948
SN - 1099-0682
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2012_Huang,
author = {Meng-Meng Huang and Marina M. Kireenko and K V Zaitsev and Yuri F. Oprunenko and Andrei V. Churakov and Judith A. Howard and Elmira Kh. Lermontova and Denis Sorokin and Thomas Linder and Jörg Sundermeyer and Sergey S. Karlov and Galina S. Zaitseva},
title = {Stabilized germylenes based on diethylenetriamines and related diamines: Synthesis, structures, and chemical properties},
journal = {European Journal of Inorganic Chemistry},
year = {2012},
volume = {2012},
publisher = {Wiley},
month = {jul},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201200363},
number = {23},
pages = {3712--3724},
doi = {10.1002/ejic.201200363}
}
MLA
Cite this
MLA Copy
Huang, Meng-Meng, et al. “Stabilized germylenes based on diethylenetriamines and related diamines: Synthesis, structures, and chemical properties.” European Journal of Inorganic Chemistry, vol. 2012, no. 23, Jul. 2012, pp. 3712-3724. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201200363.