Titanium(IV) Complexes Based on Tridentate N,N,O Ligands - Synthesis, Structure, and Thermal Decomposition
Publication type: Journal Article
Publication date: 2015-11-25
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
New tridentate N,N,O‐type ligands MeN(CH2CH2NHTs)(CH2CR2OH) [Ts = tosyl ; R = H, 6, (N,N,OH)H2; R = Ph, 7 (N,N,OPh)H2] were prepared. The corresponding diisopropoxide complexes (N,N,OH)Ti(OiPr)2 (8) and [N,N,OPh]Ti(OiPr)2 (9) were obtained through the reactions of 6 and 7 with Ti(OiPr)4. These complexes are thermally unstable and transform into the bisligated complexes [N,N,OH]2Ti (10) and {[N,N,OPh]Ti(OiPr)}2O (11). The molecular structures of 10 and 11 were investigated by X‐ray diffraction analysis. The synthesis of 11 from 9 as a thermal decomposition process was studied.
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Cherepakhin V. et al. Titanium(IV) Complexes Based on Tridentate N,N,O Ligands - Synthesis, Structure, and Thermal Decomposition // European Journal of Inorganic Chemistry. 2015. Vol. 2015. No. 36. pp. 5903-5912.
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Cherepakhin V., Zaitsev K. V., Oprunenko Y. F., Churakov A. V., Lermontova E. K., Zaitseva G. S., Karlov S. S. Titanium(IV) Complexes Based on Tridentate N,N,O Ligands - Synthesis, Structure, and Thermal Decomposition // European Journal of Inorganic Chemistry. 2015. Vol. 2015. No. 36. pp. 5903-5912.
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TY - JOUR
DO - 10.1002/ejic.201500881
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201500881
TI - Titanium(IV) Complexes Based on Tridentate N,N,O Ligands - Synthesis, Structure, and Thermal Decomposition
T2 - European Journal of Inorganic Chemistry
AU - Cherepakhin, Valeriy
AU - Zaitsev, K V
AU - Oprunenko, Yuri F.
AU - Churakov, Andrei V.
AU - Lermontova, Elmira Kh.
AU - Zaitseva, Galina S.
AU - Karlov, Sergey S.
PY - 2015
DA - 2015/11/25
PB - Wiley
SP - 5903-5912
IS - 36
VL - 2015
SN - 1434-1948
SN - 1099-0682
ER -
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@article{2015_Cherepakhin,
author = {Valeriy Cherepakhin and K V Zaitsev and Yuri F. Oprunenko and Andrei V. Churakov and Elmira Kh. Lermontova and Galina S. Zaitseva and Sergey S. Karlov},
title = {Titanium(IV) Complexes Based on Tridentate N,N,O Ligands - Synthesis, Structure, and Thermal Decomposition},
journal = {European Journal of Inorganic Chemistry},
year = {2015},
volume = {2015},
publisher = {Wiley},
month = {nov},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201500881},
number = {36},
pages = {5903--5912},
doi = {10.1002/ejic.201500881}
}
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MLA
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Cherepakhin, Valeriy, et al. “Titanium(IV) Complexes Based on Tridentate N,N,O Ligands - Synthesis, Structure, and Thermal Decomposition.” European Journal of Inorganic Chemistry, vol. 2015, no. 36, Nov. 2015, pp. 5903-5912. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201500881.