1,1‐ and 1,4‐Addition Reactions with 3a,6a‐Diaza‐1,4‐diphosphapentalene Containing Two‐Coordinate and Formally Divalent Phosphorus
A.F. Kornev
1
,
Vadim E Galperin
1
,
Vyacheslav V. Sushev
1
,
Evgeny V Baranov
1
,
Georgy K. Fukin
1
,
Gleb A. Abakumov
1
Publication type: Journal Article
Publication date: 2016-07-04
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
3a,6a-Diaza-1,4-diphosphapentalene (DDP) reacts with halocarbons to give addition products to one or both phosphorus atoms depending on the substrate. Chlorotriphenylmethane affords a 1,4-addition product, which slowly decomposes in solution to form the Ph3C radical and the chloro-DDP coupling product with a P–P bond. Benzyl chloride is added to one phosphorus atom to form hypervalent (trivalent, four-coordinate) phosphorus with a N···P distance (nonvalent interaction) of 2.191(2) A. A workup of the latter with GeCl2 results in a complex salt containing the GeCl3– anion and cation with covalent N–P bonding.
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Kornev A. et al. 1,1‐ and 1,4‐Addition Reactions with 3a,6a‐Diaza‐1,4‐diphosphapentalene Containing Two‐Coordinate and Formally Divalent Phosphorus // European Journal of Inorganic Chemistry. 2016. Vol. 2016. No. 22. pp. 3629-3633.
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Kornev A., Galperin V. E., Sushev V. V., Zolotareva N., Baranov E. V., Fukin G. K., Abakumov G. A. 1,1‐ and 1,4‐Addition Reactions with 3a,6a‐Diaza‐1,4‐diphosphapentalene Containing Two‐Coordinate and Formally Divalent Phosphorus // European Journal of Inorganic Chemistry. 2016. Vol. 2016. No. 22. pp. 3629-3633.
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TY - JOUR
DO - 10.1002/ejic.201600348
UR - https://doi.org/10.1002/ejic.201600348
TI - 1,1‐ and 1,4‐Addition Reactions with 3a,6a‐Diaza‐1,4‐diphosphapentalene Containing Two‐Coordinate and Formally Divalent Phosphorus
T2 - European Journal of Inorganic Chemistry
AU - Kornev, A.F.
AU - Galperin, Vadim E
AU - Sushev, Vyacheslav V.
AU - Zolotareva, Natalia
AU - Baranov, Evgeny V
AU - Fukin, Georgy K.
AU - Abakumov, Gleb A.
PY - 2016
DA - 2016/07/04
PB - Wiley
SP - 3629-3633
IS - 22
VL - 2016
SN - 1434-1948
SN - 1099-0682
ER -
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BibTex (up to 50 authors)
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@article{2016_Kornev,
author = {A.F. Kornev and Vadim E Galperin and Vyacheslav V. Sushev and Natalia Zolotareva and Evgeny V Baranov and Georgy K. Fukin and Gleb A. Abakumov},
title = {1,1‐ and 1,4‐Addition Reactions with 3a,6a‐Diaza‐1,4‐diphosphapentalene Containing Two‐Coordinate and Formally Divalent Phosphorus},
journal = {European Journal of Inorganic Chemistry},
year = {2016},
volume = {2016},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/ejic.201600348},
number = {22},
pages = {3629--3633},
doi = {10.1002/ejic.201600348}
}
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MLA
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Kornev, A.F., et al. “1,1‐ and 1,4‐Addition Reactions with 3a,6a‐Diaza‐1,4‐diphosphapentalene Containing Two‐Coordinate and Formally Divalent Phosphorus.” European Journal of Inorganic Chemistry, vol. 2016, no. 22, Jul. 2016, pp. 3629-3633. https://doi.org/10.1002/ejic.201600348.