European Journal of Inorganic Chemistry

, том 2020 , издание 21 , страницы 2055-2062

Synthesis of Cobalt-Iron Chalcogenide Clusters as Precursors for Catalysts of Oxygen Electroreduction in Alkali Media

Sergey S. Shapovalov ^{1, 2, 3, 4}

I. V. Skabitsky ^{1, 3}

Natalia A Mayorova ^{5, 6}

Andrey A. Shiryaev ^{5, 6}

A. A. Shiryaev ^{5, 6, 7, 8}

V. A. Grinberg ^{5, 6}

Скрыть аффилиации авторов Показать аффилиации авторов: 8 аффилиаций

N.S. Kurnakov Institute of General and Inorganic Chemistry The Russian Academy of Sciences Leninsky Ave. 31 119991 Moscow Russian Federation |

National Research University Higher School of Economics Vavilova St. 7 117312 Moscow Russian Federation |

N.S. Kurnakov Institute of General and Inorganic Chemistry the Russian Academy of Sciences Leninsky Ave. 31 119991 Moscow Russian Federation |

⁴

National Research University Higher School of Economics Vavilova St. 7 117312 Moscow Russian Federation |

⁵

Frumkin Institute of Physical Chemistry and Electrochemistry The Russian Academy of Sciences Leninsky Ave. 31 119991 Moscow Russian Federation |

⁶

Frumkin Institute of Physical Chemistry and Electrochemistry The Russian Academy of Sciences Leninsky Ave. 31 119991 Moscow Russian Federation |

⁷

Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry The Russian Academy of Sciences Staromonetny per, 35 119017 Moscow Russian Federation |

⁸

Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry The Russian Academy of Sciences Staromonetny per, 35 119017 Moscow Russian Federation |

Тип публикации: Journal Article

Дата публикации: 2020-05-26

Wiley

European Journal of Inorganic Chemistry

scimago Q2

wos Q3

БС2

SJR: 0.459

CiteScore: 3.9

Impact factor: 2.0

ISSN: 14341948, 10990682

DOI: 10.1002/ejic.202000140

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Inorganic Chemistry

Краткое описание

New cobalt‐iron chalcogenide clusters C₅HMe₄Co(CO)E₂Fe₂(CO)₆ (E = Se, Te) were prepared and characterized by IR and NMR spectroscopy; their structures were determined by single‐crystal XRD. Catalysts consisting of nanoparticles of bimetallic chalcogenides of cobalt and iron deposited on highly dispersed carbon black Vulcan XC‐72 were made from the synthesized clusters. Structural characteristics of these catalysts were assessed using X‐ray phase analysis (XRD), microprobe analysis (EDX), and transmission electron microscopy (TEM). It was shown that on the obtained catalysts oxygen electroreduction reaction in alkaline medium proceeds according to a four‐electron mechanism, and the catalysts are tolerant to methanol presence.

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Colloids and Surfaces A: Physicochemical and Engineering Aspects	Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2, 22.22% Colloids and Surfaces A: Physicochemical and Engineering Aspects 2 публикации, 22.22%
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Protection of Metals and Physical Chemistry of Surfaces	Protection of Metals and Physical Chemistry of Surfaces, 1, 11.11% Protection of Metals and Physical Chemistry of Surfaces 1 публикация, 11.11%
Electrochimica Acta	Electrochimica Acta, 1, 11.11% Electrochimica Acta 1 публикация, 11.11%
International Journal of Hydrogen Energy	International Journal of Hydrogen Energy, 1, 11.11% International Journal of Hydrogen Energy 1 публикация, 11.11%
Polyhedron	Polyhedron, 1, 11.11% Polyhedron 1 публикация, 11.11%
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Shapovalov S. S. et al. Synthesis of Cobalt-Iron Chalcogenide Clusters as Precursors for Catalysts of Oxygen Electroreduction in Alkali Media // European Journal of Inorganic Chemistry. 2020. Vol. 2020. No. 21. pp. 2055-2062.

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Shapovalov S. S., Skabitsky I. V., Mayorova N. A., Shiryaev A. A., Shiryaev A. A., Grinberg V. A. Synthesis of Cobalt-Iron Chalcogenide Clusters as Precursors for Catalysts of Oxygen Electroreduction in Alkali Media // European Journal of Inorganic Chemistry. 2020. Vol. 2020. No. 21. pp. 2055-2062.

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TY - JOUR

DO - 10.1002/ejic.202000140

UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202000140

TI - Synthesis of Cobalt-Iron Chalcogenide Clusters as Precursors for Catalysts of Oxygen Electroreduction in Alkali Media

T2 - European Journal of Inorganic Chemistry

AU - Shapovalov, Sergey S.

AU - Skabitsky, I. V.

AU - Mayorova, Natalia A

AU - Shiryaev, Andrey A.

AU - Shiryaev, A. A.

AU - Grinberg, V. A.

PY - 2020

DA - 2020/05/26

PB - Wiley

SP - 2055-2062

IS - 21

VL - 2020

SN - 1434-1948

SN - 1099-0682

ER -

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@article{2020_Shapovalov,

author = {Sergey S. Shapovalov and I. V. Skabitsky and Natalia A Mayorova and Andrey A. Shiryaev and A. A. Shiryaev and V. A. Grinberg},

title = {Synthesis of Cobalt-Iron Chalcogenide Clusters as Precursors for Catalysts of Oxygen Electroreduction in Alkali Media},

journal = {European Journal of Inorganic Chemistry},

year = {2020},

volume = {2020},

publisher = {Wiley},

month = {may},

url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202000140},

number = {21},

pages = {2055--2062},

doi = {10.1002/ejic.202000140}

}

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Shapovalov, Sergey S., et al. “Synthesis of Cobalt-Iron Chalcogenide Clusters as Precursors for Catalysts of Oxygen Electroreduction in Alkali Media.” European Journal of Inorganic Chemistry, vol. 2020, no. 21, May. 2020, pp. 2055-2062. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202000140.