Stimuli‐Responsive Emission of Dinuclear Rhombic Copper(I) Iodide Complexes Having Triphenylarsine and N‐Heteroaromatic Co‐Ligands
Publication type: Journal Article
Publication date: 2020-08-30
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
Copper(I) iodide complexes of triphenylarsine with a series of N‐heteroaromatic co‐ligands, i.e., pyridine, 2‐picoline, 2,6‐lutidine, and quinoline, were synthesized. The structures of the complexes were analyzed by X‐ray crystallography, which revealed that they adopted dinuclear rhombic structures. It was found that the arsenic atom effectively worked for forming shorter cuprophilic interaction when compared with the corresponding triphenylphosphine complex. The N‐heteroaromatic co‐ligand highly affected Cu–Cu interactions, denoted as cuprophilic interactions, as well as emission behaviors. In addition, the emission color and/or efficiency were altered by thermal and mechanical stimuli, and the responsiveness was dependent on the complex structure.
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Kobayashi R. et al. Stimuli‐Responsive Emission of Dinuclear Rhombic Copper(I) Iodide Complexes Having Triphenylarsine and N‐Heteroaromatic Co‐Ligands // European Journal of Inorganic Chemistry. 2020. Vol. 2020. No. 37. pp. 3548-3553.
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Kobayashi R., Imoto H., Naka K. Stimuli‐Responsive Emission of Dinuclear Rhombic Copper(I) Iodide Complexes Having Triphenylarsine and N‐Heteroaromatic Co‐Ligands // European Journal of Inorganic Chemistry. 2020. Vol. 2020. No. 37. pp. 3548-3553.
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RIS
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TY - JOUR
DO - 10.1002/ejic.202000644
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202000644
TI - Stimuli‐Responsive Emission of Dinuclear Rhombic Copper(I) Iodide Complexes Having Triphenylarsine and N‐Heteroaromatic Co‐Ligands
T2 - European Journal of Inorganic Chemistry
AU - Kobayashi, Ryosuke
AU - Imoto, Hiroaki
AU - Naka, Kensuke
PY - 2020
DA - 2020/08/30
PB - Wiley
SP - 3548-3553
IS - 37
VL - 2020
SN - 1434-1948
SN - 1099-0682
ER -
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BibTex (up to 50 authors)
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@article{2020_Kobayashi,
author = {Ryosuke Kobayashi and Hiroaki Imoto and Kensuke Naka},
title = {Stimuli‐Responsive Emission of Dinuclear Rhombic Copper(I) Iodide Complexes Having Triphenylarsine and N‐Heteroaromatic Co‐Ligands},
journal = {European Journal of Inorganic Chemistry},
year = {2020},
volume = {2020},
publisher = {Wiley},
month = {aug},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202000644},
number = {37},
pages = {3548--3553},
doi = {10.1002/ejic.202000644}
}
Cite this
MLA
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Kobayashi, Ryosuke, et al. “Stimuli‐Responsive Emission of Dinuclear Rhombic Copper(I) Iodide Complexes Having Triphenylarsine and N‐Heteroaromatic Co‐Ligands.” European Journal of Inorganic Chemistry, vol. 2020, no. 37, Aug. 2020, pp. 3548-3553. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202000644.