Europium (II) Sulfate EuSO4: Synthesis Methods, Crystal and Electronic Structure, Luminescence Properties
Yuriy Denisenko
1, 2, 3
,
Alexander E. Sedykh
2
,
Aleksandr S Oreshonkov
4, 5
,
Maxim S. Molokeev
6, 7, 8
,
Nikita O Azarapin
3
,
Elena I Salnikova
3, 9
,
Olga D Chimitova
10
,
Oleg V. Andreev
3, 11
,
Illaria A Razumkova
3
,
Klaus Müller-Buschbaum
2, 12
Publication type: Journal Article
Publication date: 2022-03-15
scimago Q2
wos Q3
SJR: 0.459
CiteScore: 3.9
Impact factor: 2.0
ISSN: 14341948, 10990682
Inorganic Chemistry
Abstract
In the present work, we report on the synthesis of EuSO4 powders by two different methods using EuS as starting material. The compound EuSO4 contains divalent europium and crystallizes in the orthorhombic crystal system, space group Pnma with parameters close to SrSO4. The compound exhibits near isotropic thermal expansion over the temperature range 300–700 K. EuSO4 was examined by Raman, Fourier‐transform infrared absorption and luminescence spectroscopy methods. EuSO4 is found to be an indirect bandgap material with a bandgap close to direct electronic transition. The emission lifetime of divalent europium d‐f emission in EuSO4 shows an unusual behavior for stoichiometric compounds, as it shortens upon cooling from 1.11(1) μs at room temperature to 0.44(1) μs at 77 K.
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12
Total citations:
12
Citations from 2025:
4
(33.33%)
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Denisenko Y. et al. Europium (II) Sulfate EuSO4: Synthesis Methods, Crystal and Electronic Structure, Luminescence Properties // European Journal of Inorganic Chemistry. 2022. Vol. 2022. No. 12.
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Denisenko Y., Sedykh A. E., Oreshonkov A. S., Molokeev M. S., Azarapin N. O., Salnikova E. I., Chimitova O. D., Andreev O. V., Razumkova I. A., Müller-Buschbaum K. Europium (II) Sulfate EuSO4: Synthesis Methods, Crystal and Electronic Structure, Luminescence Properties // European Journal of Inorganic Chemistry. 2022. Vol. 2022. No. 12.
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TY - JOUR
DO - 10.1002/ejic.202200043
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202200043
TI - Europium (II) Sulfate EuSO4: Synthesis Methods, Crystal and Electronic Structure, Luminescence Properties
T2 - European Journal of Inorganic Chemistry
AU - Denisenko, Yuriy
AU - Sedykh, Alexander E.
AU - Oreshonkov, Aleksandr S
AU - Molokeev, Maxim S.
AU - Azarapin, Nikita O
AU - Salnikova, Elena I
AU - Chimitova, Olga D
AU - Andreev, Oleg V.
AU - Razumkova, Illaria A
AU - Müller-Buschbaum, Klaus
PY - 2022
DA - 2022/03/15
PB - Wiley
IS - 12
VL - 2022
SN - 1434-1948
SN - 1099-0682
ER -
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BibTex (up to 50 authors)
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@article{2022_Denisenko,
author = {Yuriy Denisenko and Alexander E. Sedykh and Aleksandr S Oreshonkov and Maxim S. Molokeev and Nikita O Azarapin and Elena I Salnikova and Olga D Chimitova and Oleg V. Andreev and Illaria A Razumkova and Klaus Müller-Buschbaum},
title = {Europium (II) Sulfate EuSO4: Synthesis Methods, Crystal and Electronic Structure, Luminescence Properties},
journal = {European Journal of Inorganic Chemistry},
year = {2022},
volume = {2022},
publisher = {Wiley},
month = {mar},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202200043},
number = {12},
doi = {10.1002/ejic.202200043}
}