A Novel Approach to 2‐Chloro‐2‐fluorostyrenes
Publication type: Journal Article
Publication date: 2002-12-18
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
A new general catalytic olefination reaction (COR) of aromatic and heteroaromatic aldehydes and ketones was applied to synthesise 2‐chloro‐2‐fluorostyrenes. The two‐stage procedure includes the transformation of carbonyl compounds into hydrazones followed by treatment with CFCl3 mediated by copper catalysis. Trichlorofluoromethane was used as a chlorofluoromethylene transfer reagent. The reaction proceeds stereoselectively and the target alkenes were obtained in high yield. A proposed mechanism for the reaction is discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
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37
Total citations:
37
Citations from 2024:
1
(2.78%)
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GOST
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Nenajdenko V. G. et al. A Novel Approach to 2‐Chloro‐2‐fluorostyrenes // European Journal of Organic Chemistry. 2002. Vol. 2003. No. 2. pp. 302-308.
GOST all authors (up to 50)
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Nenajdenko V. G., Shastin A. V., Korotchenko V. N., Varseev G. N., Balenkova E. S. A Novel Approach to 2‐Chloro‐2‐fluorostyrenes // European Journal of Organic Chemistry. 2002. Vol. 2003. No. 2. pp. 302-308.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/ejoc.200390033
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.200390033
TI - A Novel Approach to 2‐Chloro‐2‐fluorostyrenes
T2 - European Journal of Organic Chemistry
AU - Nenajdenko, Valentine G.
AU - Shastin, Alexey V.
AU - Korotchenko, Vasily N.
AU - Varseev, Georgy N.
AU - Balenkova, Elisabeth S.
PY - 2002
DA - 2002/12/18
PB - Wiley
SP - 302-308
IS - 2
VL - 2003
SN - 1434-193X
SN - 1099-0690
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2002_Nenajdenko,
author = {Valentine G. Nenajdenko and Alexey V. Shastin and Vasily N. Korotchenko and Georgy N. Varseev and Elisabeth S. Balenkova},
title = {A Novel Approach to 2‐Chloro‐2‐fluorostyrenes},
journal = {European Journal of Organic Chemistry},
year = {2002},
volume = {2003},
publisher = {Wiley},
month = {dec},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.200390033},
number = {2},
pages = {302--308},
doi = {10.1002/ejoc.200390033}
}
Cite this
MLA
Copy
Nenajdenko, Valentine G., et al. “A Novel Approach to 2‐Chloro‐2‐fluorostyrenes.” European Journal of Organic Chemistry, vol. 2003, no. 2, Dec. 2002, pp. 302-308. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.200390033.