Palladium-catalyzed arylation of linear and cyclic polyamines
Publication type: Journal Article
Publication date: 2005-01-11
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
Synthetic protocols for the palladium-catalyzed arylation of various linear and cyclic polyamines and polyoxapolyamines has been worked out. Pd(0) and Pd(II) complexes with such phosphine ligands as dppf, BINAP, PPF-OMe, P(tBu) 3 , 2-ditert-butylphosphino- 1,1'-biphenyl have been explored in the catalytic amination reactions. Monoamination of chloro-, bromo-, and iodoarenes with di-, tri-, and tetraamines have been carried out, condi- tions for di- and polyarylation of linear polyamines have been elaborated. Successful aryla- tion of 1,4,7,10-tetraazacyclododecane (cyclene) and 1,4,8,11-tetraazacyclotetradecane (cy- clam) have been conducted. Intramolecular diamination of dihaloarenes such as 1,2-dibromobenzene, 2,6-dichlorobromobenzene, 1,3-dibromobenzene, 1,8-dichloro- anthracene, 1,8-dichloroanthraquinone, 1,5-dichloroanthracene, and 1,5-dichloroanthra- quinone afforded corresponding polyazamacrocycles containing arene moieties. For the first time, a convenient one-pot synthesis of the face-to-face arranged bismacrocyclic systems has been carried out.
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53
Total citations:
53
Citations from 2024:
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(5%)
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GOST
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Beletskaya I. P. et al. Palladium-catalyzed arylation of linear and cyclic polyamines // European Journal of Organic Chemistry. 2005. Vol. 2005. No. 2. pp. 261-280.
GOST all authors (up to 50)
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Beletskaya I. P., Bessmertnykh A., Averin A. A., Denat F., Guilard R. Palladium-catalyzed arylation of linear and cyclic polyamines // European Journal of Organic Chemistry. 2005. Vol. 2005. No. 2. pp. 261-280.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/ejoc.200400456
UR - https://doi.org/10.1002/ejoc.200400456
TI - Palladium-catalyzed arylation of linear and cyclic polyamines
T2 - European Journal of Organic Chemistry
AU - Beletskaya, Irina P.
AU - Bessmertnykh, Allag
AU - Averin, Alexey A
AU - Denat, Franck
AU - Guilard, Roger
PY - 2005
DA - 2005/01/11
PB - Wiley
SP - 261-280
IS - 2
VL - 2005
SN - 1434-193X
SN - 1099-0690
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2005_Beletskaya,
author = {Irina P. Beletskaya and Allag Bessmertnykh and Alexey A Averin and Franck Denat and Roger Guilard},
title = {Palladium-catalyzed arylation of linear and cyclic polyamines},
journal = {European Journal of Organic Chemistry},
year = {2005},
volume = {2005},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/ejoc.200400456},
number = {2},
pages = {261--280},
doi = {10.1002/ejoc.200400456}
}
Cite this
MLA
Copy
Beletskaya, Irina P., et al. “Palladium-catalyzed arylation of linear and cyclic polyamines.” European Journal of Organic Chemistry, vol. 2005, no. 2, Jan. 2005, pp. 261-280. https://doi.org/10.1002/ejoc.200400456.
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