, volume 2007 , issue 35 , pages 5861-5866

Highly Regio- and Stereoselective (2+3) Cycloadditions of Azomethine Ylides to (70)Fullerene

Pavel A. Troshin ¹

A. S. Peregudov ²

Svetlana M. Peregudova ²

Rimma N. Lyubovskaya ¹

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Institute of Problems of Chemical Physics of Russian Academy of Sciences, Semenov Prospect 1, Chernogolovka, Moscow region 142432, Russia, Fax: +7-496-522-18-52 |

A. N. Nesmeyanov Institute of Organoelement Compounds, 1 Vavylova St. 28, B-334, Moscow, 119991, Russia |

Publication type: Journal Article

Publication date: 2007-12-01

Wiley

European Journal of Organic Chemistry

scimago Q2

wos Q2

SJR: 0.558

CiteScore: 4.3

Impact factor: 2.7

ISSN: 1434193X, 10990690

DOI: 10.1002/ejoc.200700511

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Organic Chemistry

Physical and Theoretical Chemistry

Abstract

Picolylamines and aromatic aldehydes were used as reagents to generate azomethine ylides that undergo highly regioand stereoselective [2+3] cycloaddition reactions with [70]fullerene. Isolated pyrrolidinofullerenes were products of the ylide addition across the most reactive 8,25-double bond in the carbon cage; other regioisomers were observed in small amounts or did not form at all. These reactions demonstrated unusually high stereoselectivity: 2,5-disubstituted

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Faraonov Maxim

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PhD in Chemistry

59 publications, 423 citations, 2 reviews

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Federal Research Center of Problem of Chemical Physics and Medicinal Chemistry RAS

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Troshin P. A. et al. Highly Regio- and Stereoselective (2+3) Cycloadditions of Azomethine Ylides to (70)Fullerene // European Journal of Organic Chemistry. 2007. Vol. 2007. No. 35. pp. 5861-5866.

GOST all authors (up to 50) Copy

Troshin P. A., Peregudov A. S., Peregudova S. M., Lyubovskaya R. N. Highly Regio- and Stereoselective (2+3) Cycloadditions of Azomethine Ylides to (70)Fullerene // European Journal of Organic Chemistry. 2007. Vol. 2007. No. 35. pp. 5861-5866.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1002/ejoc.200700511

UR - https://doi.org/10.1002/ejoc.200700511

TI - Highly Regio- and Stereoselective (2+3) Cycloadditions of Azomethine Ylides to (70)Fullerene

T2 - European Journal of Organic Chemistry

AU - Troshin, Pavel A.

AU - Peregudov, A. S.

AU - Peregudova, Svetlana M.

AU - Lyubovskaya, Rimma N.

PY - 2007

DA - 2007/12/01

PB - Wiley

SP - 5861-5866

IS - 35

VL - 2007

SN - 1434-193X

SN - 1099-0690

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2007_Troshin,

author = {Pavel A. Troshin and A. S. Peregudov and Svetlana M. Peregudova and Rimma N. Lyubovskaya},

title = {Highly Regio- and Stereoselective (2+3) Cycloadditions of Azomethine Ylides to (70)Fullerene},

journal = {European Journal of Organic Chemistry},

year = {2007},

volume = {2007},

publisher = {Wiley},

month = {dec},

url = {https://doi.org/10.1002/ejoc.200700511},

number = {35},

pages = {5861--5866},

doi = {10.1002/ejoc.200700511}

}

MLA

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Troshin, Pavel A., et al. “Highly Regio- and Stereoselective (2+3) Cycloadditions of Azomethine Ylides to (70)Fullerene.” European Journal of Organic Chemistry, vol. 2007, no. 35, Dec. 2007, pp. 5861-5866. https://doi.org/10.1002/ejoc.200700511.