European Journal of Organic Chemistry, volume 2010, issue 6, pages 1169-1175
Nitrogen-Rich Polymers Based on 5-Bromo-1-vinyl-1H-tetrazole
Publication type: Journal Article
Publication date: 2010-01-08
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
Nitrogen-rich polymers with contents of nitrogen between 50 and 60 % were synthesized by radical polymerization using 1-(1-vinyl-1H-tetrazol-5-yl)hydrazine and 1-methyl-1-(1-vinyl-1H-tetrazol-5-yl)hydrazine. The monomers were obtained by substitution reactions of hydrazine derivatives and 5-bromo-1-vinyl-1H-tetrazole. Moreover, the poly-1-(1-vinyl-1H-tetrazol-5-yl)hydrazine was converted into the corresponding 5-azidotetrazolyl-containing polymer by the reaction with sodium nitrite. The polymers were characterized by measurements of the molecular weights, by vibrational spectroscopy (IR) and elemental analysis. The thermal stability was determined by differential scanning calorimetry and the sensitivity towards friction and impact were determined by BAM standards. The energetic properties were investigated by bomb calorimetric measurements and calculations with the EXPLO5 software. The high stability of the polymers towards impact and friction, along with their sufficient thermal stability (175―279 °C) and moderate energetic characters renders these polymers into promising compounds for an application as environmently friendly nitrogen-rich polymers.
Top-30
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1 publication, 4.76%
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1 publication, 4.76%
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1 publication, 4.76%
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1 publication, 4.76%
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Citations by publishers
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5
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Wiley
5 publications, 23.81%
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Royal Society of Chemistry (RSC)
4 publications, 19.05%
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Elsevier
3 publications, 14.29%
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Springer Nature
2 publications, 9.52%
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American Chemical Society (ACS)
2 publications, 9.52%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 4.76%
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Pleiades Publishing
1 publication, 4.76%
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Belarusian State University
1 publication, 4.76%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 4.76%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Klapötke T. M., Sproll S. M. Nitrogen-Rich Polymers Based on 5-Bromo-1-vinyl-1H-tetrazole // European Journal of Organic Chemistry. 2010. Vol. 2010. No. 6. pp. 1169-1175.
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Klapötke T. M., Sproll S. M. Nitrogen-Rich Polymers Based on 5-Bromo-1-vinyl-1H-tetrazole // European Journal of Organic Chemistry. 2010. Vol. 2010. No. 6. pp. 1169-1175.
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TY - JOUR
DO - 10.1002/ejoc.200901226
UR - https://doi.org/10.1002/ejoc.200901226
TI - Nitrogen-Rich Polymers Based on 5-Bromo-1-vinyl-1H-tetrazole
T2 - European Journal of Organic Chemistry
AU - Klapötke, Thomas M.
AU - Sproll, Stefan M.
PY - 2010
DA - 2010/01/08 00:00:00
PB - Wiley
SP - 1169-1175
IS - 6
VL - 2010
SN - 1434-193X
SN - 1099-0690
ER -
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@article{2010_Klapötke,
author = {Thomas M. Klapötke and Stefan M. Sproll},
title = {Nitrogen-Rich Polymers Based on 5-Bromo-1-vinyl-1H-tetrazole},
journal = {European Journal of Organic Chemistry},
year = {2010},
volume = {2010},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/ejoc.200901226},
number = {6},
pages = {1169--1175},
doi = {10.1002/ejoc.200901226}
}
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Klapötke, Thomas M., and Stefan M. Sproll. “Nitrogen-Rich Polymers Based on 5-Bromo-1-vinyl-1H-tetrazole.” European Journal of Organic Chemistry, vol. 2010, no. 6, Jan. 2010, pp. 1169-1175. https://doi.org/10.1002/ejoc.200901226.