Titanium-Catalyzed [6π+2π]-Cycloaddition of Alkynes and Allenes to 7-Substituted 1,3,5-Cycloheptatrienes
Publication type: Journal Article
Publication date: 2015-06-09
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
The reaction of 7-alkyl(allyl,phenyl)-1,3,5-cycloheptatrienes with alkynes and allenes, catalyzed by the two-component Ti(acac)2Cl2–Et2AlCl system, resulting in the formation of substituted bicyclo[4.2.1]nona-2,4-dienes and bicyclo[4.2.1]nona-2,4,7-trienes in up to 90 % yield, was accomplished. The structures of the obtained compounds were confirmed by X-ray diffraction and by 1H and 13C NMR spectroscopic analysis.
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GOST
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D'yakonov V. A. et al. Titanium-Catalyzed [6π+2π]-Cycloaddition of Alkynes and Allenes to 7-Substituted 1,3,5-Cycloheptatrienes // European Journal of Organic Chemistry. 2015. Vol. 2015. No. 20. pp. 4464-4470.
GOST all authors (up to 50)
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D'yakonov V. A., Kadikova G. N., Kolokoltsev D. I., Ramazanov I. R., Dzhemilev U. M. Titanium-Catalyzed [6π+2π]-Cycloaddition of Alkynes and Allenes to 7-Substituted 1,3,5-Cycloheptatrienes // European Journal of Organic Chemistry. 2015. Vol. 2015. No. 20. pp. 4464-4470.
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RIS
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TY - JOUR
DO - 10.1002/ejoc.201500442
UR - https://doi.org/10.1002/ejoc.201500442
TI - Titanium-Catalyzed [6π+2π]-Cycloaddition of Alkynes and Allenes to 7-Substituted 1,3,5-Cycloheptatrienes
T2 - European Journal of Organic Chemistry
AU - D'yakonov, Vladimir A
AU - Kadikova, Gulnara N.
AU - Kolokoltsev, Dmitry I
AU - Ramazanov, Ilfir R
AU - Dzhemilev, Usein M
PY - 2015
DA - 2015/06/09
PB - Wiley
SP - 4464-4470
IS - 20
VL - 2015
SN - 1434-193X
SN - 1099-0690
ER -
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BibTex (up to 50 authors)
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@article{2015_D'yakonov,
author = {Vladimir A D'yakonov and Gulnara N. Kadikova and Dmitry I Kolokoltsev and Ilfir R Ramazanov and Usein M Dzhemilev},
title = {Titanium-Catalyzed [6π+2π]-Cycloaddition of Alkynes and Allenes to 7-Substituted 1,3,5-Cycloheptatrienes},
journal = {European Journal of Organic Chemistry},
year = {2015},
volume = {2015},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002/ejoc.201500442},
number = {20},
pages = {4464--4470},
doi = {10.1002/ejoc.201500442}
}
Cite this
MLA
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D'yakonov, Vladimir A., et al. “Titanium-Catalyzed [6π+2π]-Cycloaddition of Alkynes and Allenes to 7-Substituted 1,3,5-Cycloheptatrienes.” European Journal of Organic Chemistry, vol. 2015, no. 20, Jun. 2015, pp. 4464-4470. https://doi.org/10.1002/ejoc.201500442.