Palladium(II) Complexes of the Hemilabile Pincer Ligand PPh(o-C6H4SMe)2as Highly Active and Recyclable Mizoroki-Heck Catalysts
Asunción Luquin
1, 2
,
Noelia Castillo
3
,
E. Cerrada
3
,
Francisco L. Merchan
3
,
Julián Garrido
2
,
Mariano Laguna
3
2
Publication type: Journal Article
Publication date: 2015-12-15
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
PdII complexes with PPh(o-C6H4SMe)2 acting as a pincer ligand in an S,S′,P- or S,P-coordination mode have been synthesized. The complexes include [PdCl2{PPh(o-C6H4SMe)2}] (1), [Pd(Me)Cl{PPh(o-C6H4SMe)2}] (2), and [Pd(X){PPh(o-C6H4SMe)2}]A [A = CF3SO3, X = Cl (3); A = CF3SO3, Me (4); A = PF6, X = Me (5)]. Insertion of CO into the Pd–Me bond of these complexes leads to [Pd(COMe)Cl{PPh(o-C6H4SMe)2}] (6) and [Pd(COMe){PPh(o-C6H4SMe)2}]A [A = CF3SO3 (7); A = PF6 (8)]. Some of these complexes are good Mizoroki–Heck catalysts (for the reactions between iodobenzene and methyl acrylate or styrene). The most active catalyst was found to be [Pd(Me)Cl{PPh(o-C6H4SMe)2}] (2). This catalyst could be retained on a silica gel column, recovered, and reused several times without losing activity.
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Total citations:
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Citations from 2025:
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Luquin A. et al. Palladium(II) Complexes of the Hemilabile Pincer Ligand PPh(o-C6H4SMe)2as Highly Active and Recyclable Mizoroki-Heck Catalysts // European Journal of Organic Chemistry. 2015. Vol. 2016. No. 4. pp. 789-798.
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Luquin A., Castillo N., Cerrada E., Merchan F. L., Garrido J., Laguna M. Palladium(II) Complexes of the Hemilabile Pincer Ligand PPh(o-C6H4SMe)2as Highly Active and Recyclable Mizoroki-Heck Catalysts // European Journal of Organic Chemistry. 2015. Vol. 2016. No. 4. pp. 789-798.
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TY - JOUR
DO - 10.1002/ejoc.201501354
UR - https://doi.org/10.1002/ejoc.201501354
TI - Palladium(II) Complexes of the Hemilabile Pincer Ligand PPh(o-C6H4SMe)2as Highly Active and Recyclable Mizoroki-Heck Catalysts
T2 - European Journal of Organic Chemistry
AU - Luquin, Asunción
AU - Castillo, Noelia
AU - Cerrada, E.
AU - Merchan, Francisco L.
AU - Garrido, Julián
AU - Laguna, Mariano
PY - 2015
DA - 2015/12/15
PB - Wiley
SP - 789-798
IS - 4
VL - 2016
SN - 1434-193X
SN - 1099-0690
ER -
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BibTex (up to 50 authors)
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@article{2015_Luquin,
author = {Asunción Luquin and Noelia Castillo and E. Cerrada and Francisco L. Merchan and Julián Garrido and Mariano Laguna},
title = {Palladium(II) Complexes of the Hemilabile Pincer Ligand PPh(o-C6H4SMe)2as Highly Active and Recyclable Mizoroki-Heck Catalysts},
journal = {European Journal of Organic Chemistry},
year = {2015},
volume = {2016},
publisher = {Wiley},
month = {dec},
url = {https://doi.org/10.1002/ejoc.201501354},
number = {4},
pages = {789--798},
doi = {10.1002/ejoc.201501354}
}
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MLA
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Luquin, Asunción, et al. “Palladium(II) Complexes of the Hemilabile Pincer Ligand PPh(o-C6H4SMe)2as Highly Active and Recyclable Mizoroki-Heck Catalysts.” European Journal of Organic Chemistry, vol. 2016, no. 4, Dec. 2015, pp. 789-798. https://doi.org/10.1002/ejoc.201501354.