Oxypalladation Initiating the Oxidative Heck Reaction with Alkenyl Alcohols: Synthesis of Isocoumarin-Alkanones
Тип публикации: Journal Article
Дата публикации: 2016-01-05
SCImago Q2
WOS Q2
БС2
SJR: 0.497
CiteScore: 4.2
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Highly regioselective nucleopalladation for the oxidative coupling of internal alkynes with alkenyl alcohols by using green and low-costing oxygen as the sole oxidant was investigated. This one-pot cascade cyclization proceeds through Pd-catalyzed intramolecular C–O bond cyclization, insertion of nonbiased alkenyl alcohols, β-H elimination, and reinsertion of a HPdX species, which is finally transferred to the target ketones. This method has the advantages of mild conditions, good functional group tolerance, and can be performed with unactivated alkenes to afford isocoumarin derivatives.
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Zheng M. et al. Oxypalladation Initiating the Oxidative Heck Reaction with Alkenyl Alcohols: Synthesis of Isocoumarin-Alkanones // European Journal of Organic Chemistry. 2016. Vol. 2016. No. 4. pp. 663-667.
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Zheng M., Huang L., Tong Q., Wu W., Jiang H. Oxypalladation Initiating the Oxidative Heck Reaction with Alkenyl Alcohols: Synthesis of Isocoumarin-Alkanones // European Journal of Organic Chemistry. 2016. Vol. 2016. No. 4. pp. 663-667.
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TY - JOUR
DO - 10.1002/ejoc.201501451
UR - https://doi.org/10.1002/ejoc.201501451
TI - Oxypalladation Initiating the Oxidative Heck Reaction with Alkenyl Alcohols: Synthesis of Isocoumarin-Alkanones
T2 - European Journal of Organic Chemistry
AU - Zheng, Meifang
AU - Huang, Liangbin
AU - Tong, Qizhen
AU - Wu, Wanqing
AU - Jiang, Huanfeng
PY - 2016
DA - 2016/01/05
PB - Wiley
SP - 663-667
IS - 4
VL - 2016
SN - 1434-193X
SN - 1099-0690
ER -
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BibTex (до 50 авторов)
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@article{2016_Zheng,
author = {Meifang Zheng and Liangbin Huang and Qizhen Tong and Wanqing Wu and Huanfeng Jiang},
title = {Oxypalladation Initiating the Oxidative Heck Reaction with Alkenyl Alcohols: Synthesis of Isocoumarin-Alkanones},
journal = {European Journal of Organic Chemistry},
year = {2016},
volume = {2016},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1002/ejoc.201501451},
number = {4},
pages = {663--667},
doi = {10.1002/ejoc.201501451}
}
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MLA
Скопировать
Zheng, Meifang, et al. “Oxypalladation Initiating the Oxidative Heck Reaction with Alkenyl Alcohols: Synthesis of Isocoumarin-Alkanones.” European Journal of Organic Chemistry, vol. 2016, no. 4, Jan. 2016, pp. 663-667. https://doi.org/10.1002/ejoc.201501451.
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