Solvent-Free Buchwald-Hartwig (Hetero)arylation of Anilines, Diarylamines, and Dialkylamines Mediated by Expanded-Ring N-Heterocyclic Carbene Palladium Complexes
Тип публикации: Journal Article
Дата публикации: 2016-03-15
SCImago Q2
WOS Q2
БС2
SJR: 0.497
CiteScore: 4.2
Impact factor: 2.8
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Краткое описание
A highly efficient solvent-free protocol for the Buchwald–Hartwig (hetero)arylation of anilines, diarylamines, and dialkylamines mediated by the expanded-ring N-heterocyclic carbene palladium complex (THP-Dipp)Pd(cinn)Cl [THP-Dipp = 1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene; cinn = cinnamyl, 3-phenylallyl] was developed. The catalytic protocol was efficient for the coupling of amines and (hetero)aryl chlorides and bromides bearing donor, acceptor, and bulky substituents.
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Topchiy M. A. et al. Solvent-Free Buchwald-Hartwig (Hetero)arylation of Anilines, Diarylamines, and Dialkylamines Mediated by Expanded-Ring N-Heterocyclic Carbene Palladium Complexes // European Journal of Organic Chemistry. 2016. Vol. 2016. No. 10. pp. 1908-1914.
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Topchiy M. A., Dzhevakov P. B., Rubina M., Morozov O. S., Asachenko A., Nechaev M. P. Solvent-Free Buchwald-Hartwig (Hetero)arylation of Anilines, Diarylamines, and Dialkylamines Mediated by Expanded-Ring N-Heterocyclic Carbene Palladium Complexes // European Journal of Organic Chemistry. 2016. Vol. 2016. No. 10. pp. 1908-1914.
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TY - JOUR
DO - 10.1002/ejoc.201501616
UR - https://doi.org/10.1002/ejoc.201501616
TI - Solvent-Free Buchwald-Hartwig (Hetero)arylation of Anilines, Diarylamines, and Dialkylamines Mediated by Expanded-Ring N-Heterocyclic Carbene Palladium Complexes
T2 - European Journal of Organic Chemistry
AU - Topchiy, Maxim A
AU - Dzhevakov, Pavel B
AU - Rubina, Margarita
AU - Morozov, Oleg S
AU - Asachenko, Andrey
AU - Nechaev, Mikhail Petrovich
PY - 2016
DA - 2016/03/15
PB - Wiley
SP - 1908-1914
IS - 10
VL - 2016
SN - 1434-193X
SN - 1099-0690
ER -
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@article{2016_Topchiy,
author = {Maxim A Topchiy and Pavel B Dzhevakov and Margarita Rubina and Oleg S Morozov and Andrey Asachenko and Mikhail Petrovich Nechaev},
title = {Solvent-Free Buchwald-Hartwig (Hetero)arylation of Anilines, Diarylamines, and Dialkylamines Mediated by Expanded-Ring N-Heterocyclic Carbene Palladium Complexes},
journal = {European Journal of Organic Chemistry},
year = {2016},
volume = {2016},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/ejoc.201501616},
number = {10},
pages = {1908--1914},
doi = {10.1002/ejoc.201501616}
}
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MLA
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Topchiy, Maxim A., et al. “Solvent-Free Buchwald-Hartwig (Hetero)arylation of Anilines, Diarylamines, and Dialkylamines Mediated by Expanded-Ring N-Heterocyclic Carbene Palladium Complexes.” European Journal of Organic Chemistry, vol. 2016, no. 10, Mar. 2016, pp. 1908-1914. https://doi.org/10.1002/ejoc.201501616.
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