volume 2019 issue 26 pages 4119-4122

Reductive Bromodifluoromethylation of Nitrones Promoted by Visible Light

Publication typeJournal Article
Publication date2019-04-01
scimago Q2
wos Q2
SJR0.558
CiteScore4.3
Impact factor2.7
ISSN1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract

A method for the synthesis of bromodifluoromethyl‐substituted hydroxylamines via reaction of nitrones with dibromodifluoromethane is described. The reaction is mediated by an iridium photocatalyst activated by blue light and employs ascorbic acid as a reductant. In the products, the bromodifluoromethyl fragment can be reduced to the CHF2‐group or can be functionalized through the hydrofluoroalkylation process.

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GOST |
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GOST Copy
Dmitriev I. et al. Reductive Bromodifluoromethylation of Nitrones Promoted by Visible Light // European Journal of Organic Chemistry. 2019. Vol. 2019. No. 26. pp. 4119-4122.
GOST all authors (up to 50) Copy
Dmitriev I., Supranovich V. I., Levin V. V., Dilman A. D. Reductive Bromodifluoromethylation of Nitrones Promoted by Visible Light // European Journal of Organic Chemistry. 2019. Vol. 2019. No. 26. pp. 4119-4122.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1002/ejoc.201900274
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.201900274
TI - Reductive Bromodifluoromethylation of Nitrones Promoted by Visible Light
T2 - European Journal of Organic Chemistry
AU - Dmitriev, I. A.
AU - Supranovich, Vyacheslav I
AU - Levin, Vitalij V
AU - Dilman, Alexander D
PY - 2019
DA - 2019/04/01
PB - Wiley
SP - 4119-4122
IS - 26
VL - 2019
SN - 1434-193X
SN - 1099-0690
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Dmitriev,
author = {I. A. Dmitriev and Vyacheslav I Supranovich and Vitalij V Levin and Alexander D Dilman},
title = {Reductive Bromodifluoromethylation of Nitrones Promoted by Visible Light},
journal = {European Journal of Organic Chemistry},
year = {2019},
volume = {2019},
publisher = {Wiley},
month = {apr},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.201900274},
number = {26},
pages = {4119--4122},
doi = {10.1002/ejoc.201900274}
}
MLA
Cite this
MLA Copy
Dmitriev, I. A., et al. “Reductive Bromodifluoromethylation of Nitrones Promoted by Visible Light.” European Journal of Organic Chemistry, vol. 2019, no. 26, Apr. 2019, pp. 4119-4122. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejoc.201900274.