CF3 -Containing para -Quinone Methides for Organic Synthesis
Publication type: Journal Article
Publication date: 2020-03-30
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
PubMed ID:
32624681
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
A new family of CF3-containing para-quinone methides (CF3-QMs) was systematically investigated for its suitability in organic synthesis. Addition of different nucleophiles gives access to target molecules with a benzylic CF3-containing stereogenic center straightforwardly. The electrophilicity parameter E of the prototypical CF3-QM 2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one was determined to be -11.68 according to the Mayr scale, making it one of the most reactive quinone methides known so far.
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Metrics
18
Total citations:
18
Citations from 2025:
1
(5.88%)
Cite this
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MLA
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GOST
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Winter M. et al. CF3 -Containing para -Quinone Methides for Organic Synthesis // European Journal of Organic Chemistry. 2020. Vol. 2020. No. 25. pp. 3812-3817.
GOST all authors (up to 50)
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Winter M., Schütz R., Eitzinger A., Ofial A. R., Waser M. CF3 -Containing para -Quinone Methides for Organic Synthesis // European Journal of Organic Chemistry. 2020. Vol. 2020. No. 25. pp. 3812-3817.
Cite this
RIS
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TY - JOUR
DO - 10.1002/ejoc.202000295
UR - https://doi.org/10.1002/ejoc.202000295
TI - CF3 -Containing para -Quinone Methides for Organic Synthesis
T2 - European Journal of Organic Chemistry
AU - Winter, Michael
AU - Schütz, Roman
AU - Eitzinger, Andreas
AU - Ofial, Armin R.
AU - Waser, Mario
PY - 2020
DA - 2020/03/30
PB - Wiley
SP - 3812-3817
IS - 25
VL - 2020
PMID - 32624681
SN - 1434-193X
SN - 1099-0690
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Winter,
author = {Michael Winter and Roman Schütz and Andreas Eitzinger and Armin R. Ofial and Mario Waser},
title = {CF3 -Containing para -Quinone Methides for Organic Synthesis},
journal = {European Journal of Organic Chemistry},
year = {2020},
volume = {2020},
publisher = {Wiley},
month = {mar},
url = {https://doi.org/10.1002/ejoc.202000295},
number = {25},
pages = {3812--3817},
doi = {10.1002/ejoc.202000295}
}
Cite this
MLA
Copy
Winter, Michael, et al. “CF3 -Containing para -Quinone Methides for Organic Synthesis.” European Journal of Organic Chemistry, vol. 2020, no. 25, Mar. 2020, pp. 3812-3817. https://doi.org/10.1002/ejoc.202000295.