Efficient Multigram Approach to Acetylenes and CF 3 ‐ynones Starting from Dichloroalkenes Prepared by Catalytic Olefination Reaction (COR)
Publication type: Journal Article
Publication date: 2020-07-10
scimago Q2
wos Q2
SJR: 0.558
CiteScore: 4.3
Impact factor: 2.7
ISSN: 1434193X, 10990690
Organic Chemistry
Physical and Theoretical Chemistry
Abstract
Efficient two step approach towards terminal acetylenes was elaborated. At the first step, dichloroalkenes were prepared in up to 88 % yields by catalytic olefination reaction COR of arylaldehydes. Treatment of dichloroalkenes with nBuLi effectively led to the corresponding alkynes in up to 97 % yield. A versatile one pot procedure towards CF3-ynones was elaborated to give these products in up to 87 % yield starting from dichloroalkenes.
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9
Total citations:
9
Citations from 2024:
5
(55.55%)
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GOST
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Muzalevskiy V. M. et al. Efficient Multigram Approach to Acetylenes and CF 3 ‐ynones Starting from Dichloroalkenes Prepared by Catalytic Olefination Reaction (COR) // European Journal of Organic Chemistry. 2020. Vol. 2020. No. 27. pp. 4161-4166.
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Muzalevskiy V. M., Sizova Z. A., Diusenov A. I., Shastin A. V., Nenajdenko V. G. Efficient Multigram Approach to Acetylenes and CF 3 ‐ynones Starting from Dichloroalkenes Prepared by Catalytic Olefination Reaction (COR) // European Journal of Organic Chemistry. 2020. Vol. 2020. No. 27. pp. 4161-4166.
Cite this
RIS
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TY - JOUR
DO - 10.1002/ejoc.202000531
UR - https://doi.org/10.1002/ejoc.202000531
TI - Efficient Multigram Approach to Acetylenes and CF 3 ‐ynones Starting from Dichloroalkenes Prepared by Catalytic Olefination Reaction (COR)
T2 - European Journal of Organic Chemistry
AU - Muzalevskiy, Vasily M.
AU - Sizova, Zoia A
AU - Diusenov, Arstan I
AU - Shastin, Alexey V.
AU - Nenajdenko, Valentine G.
PY - 2020
DA - 2020/07/10
PB - Wiley
SP - 4161-4166
IS - 27
VL - 2020
SN - 1434-193X
SN - 1099-0690
ER -
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BibTex (up to 50 authors)
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@article{2020_Muzalevskiy,
author = {Vasily M. Muzalevskiy and Zoia A Sizova and Arstan I Diusenov and Alexey V. Shastin and Valentine G. Nenajdenko},
title = {Efficient Multigram Approach to Acetylenes and CF 3 ‐ynones Starting from Dichloroalkenes Prepared by Catalytic Olefination Reaction (COR)},
journal = {European Journal of Organic Chemistry},
year = {2020},
volume = {2020},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1002/ejoc.202000531},
number = {27},
pages = {4161--4166},
doi = {10.1002/ejoc.202000531}
}
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MLA
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Muzalevskiy, Vasily M., et al. “Efficient Multigram Approach to Acetylenes and CF 3 ‐ynones Starting from Dichloroalkenes Prepared by Catalytic Olefination Reaction (COR).” European Journal of Organic Chemistry, vol. 2020, no. 27, Jul. 2020, pp. 4161-4166. https://doi.org/10.1002/ejoc.202000531.